Periodic mesoporous organometallic silicas with unary or binary organometals inside the channel walls as active and reusable catalysts in aqueous organic reactions

Jianlin Huang, Fengxia Zhu, Wenhan He, Fang Zhang, Wei Wang, Hexing Li

Research output: Contribution to journalArticlepeer-review

117 Scopus citations

Abstract

(Figure Presented) A new type of heterogenized organometallic catalysts, periodic mesoporous organometallic silicas with organometals and organic groups embedded in silica walls have been developed using surfactant-directed co-condensation. These catalysts exhibit high efficiencies and strong durability in water-medium organic reactions. Moreover, a bifunctional catalyst containing both Pd(II) and Ru(II) organometals inside pore walls can catalyze the water-medium "one-pot" cascade reaction effectively. These catalysts can be conveniently recycled and reused without significant loss of catalytic activities.

Original languageEnglish (US)
Pages (from-to)1492-1493
Number of pages2
JournalJournal of the American Chemical Society
Volume132
Issue number5
DOIs
StatePublished - Feb 10 2010
Externally publishedYes

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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