One-pot synthesis of salicylaldehyde containing biaryl frameworks via an aminocatalytic Diels-Alder-retro-Diels-Alder cascade reaction of ynals with 2-pyrones

Xixi Song; Yueteng Zhang; Peng Ji; Fanxun Zeng; Fangchao Bi; Wei Wang

doi:10.1016/j.gresc.2020.05.001

One-pot synthesis of salicylaldehyde containing biaryl frameworks via an aminocatalytic Diels-Alder-retro-Diels-Alder cascade reaction of ynals with 2-pyrones

Xixi Song
, Yueteng Zhang
, Peng Ji
, Fanxun Zeng
, Fangchao Bi
, Wei Wang

Pharmacology and Toxicology

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

Salicylaldehyde containing biaryls are efficiently synthesized via an unprecedented amine promoted Diels-Alder-retro-Diels-Alder cascade reaction of ynals with 2-pyrones in good yields. The reaction is instrumentally metal-free, operationally simple and mild, and tolerates a diverse array of functional groups.

Original language	English (US)
Pages (from-to)	66-69
Number of pages	4
Journal	Green Synthesis and Catalysis
Volume	1
Issue number	1
DOIs	https://doi.org/10.1016/j.gresc.2020.05.001
State	Published - Jun 2020

Keywords

Aminocatalysis
Biaryls
Cascade reactions
Diels-Alder reaction
Organocatalysis
Ynals

ASJC Scopus subject areas

Catalysis
Biotechnology

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10.1016/j.gresc.2020.05.001

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abstract = "Salicylaldehyde containing biaryls are efficiently synthesized via an unprecedented amine promoted Diels-Alder-retro-Diels-Alder cascade reaction of ynals with 2-pyrones in good yields. The reaction is instrumentally metal-free, operationally simple and mild, and tolerates a diverse array of functional groups.",

keywords = "Aminocatalysis, Biaryls, Cascade reactions, Diels-Alder reaction, Organocatalysis, Ynals",

author = "Xixi Song and Yueteng Zhang and Peng Ji and Fanxun Zeng and Fangchao Bi and Wei Wang",

note = "Publisher Copyright: {\textcopyright} 2020 The Authors",

year = "2020",

month = jun,

doi = "10.1016/j.gresc.2020.05.001",

language = "English (US)",

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T1 - One-pot synthesis of salicylaldehyde containing biaryl frameworks via an aminocatalytic Diels-Alder-retro-Diels-Alder cascade reaction of ynals with 2-pyrones

AU - Song, Xixi

AU - Zhang, Yueteng

AU - Ji, Peng

AU - Zeng, Fanxun

AU - Bi, Fangchao

AU - Wang, Wei

PY - 2020/6

Y1 - 2020/6

N2 - Salicylaldehyde containing biaryls are efficiently synthesized via an unprecedented amine promoted Diels-Alder-retro-Diels-Alder cascade reaction of ynals with 2-pyrones in good yields. The reaction is instrumentally metal-free, operationally simple and mild, and tolerates a diverse array of functional groups.

AB - Salicylaldehyde containing biaryls are efficiently synthesized via an unprecedented amine promoted Diels-Alder-retro-Diels-Alder cascade reaction of ynals with 2-pyrones in good yields. The reaction is instrumentally metal-free, operationally simple and mild, and tolerates a diverse array of functional groups.

KW - Aminocatalysis

KW - Biaryls

KW - Cascade reactions

KW - Diels-Alder reaction

KW - Organocatalysis

KW - Ynals

UR - https://www.scopus.com/pages/publications/85115151513

UR - https://www.scopus.com/pages/publications/85115151513#tab=citedBy

U2 - 10.1016/j.gresc.2020.05.001

DO - 10.1016/j.gresc.2020.05.001

M3 - Article

AN - SCOPUS:85115151513

SN - 2666-5549

VL - 1

SP - 66

EP - 69

JO - Green Synthesis and Catalysis

JF - Green Synthesis and Catalysis

IS - 1

ER -

One-pot synthesis of salicylaldehyde containing biaryl frameworks via an aminocatalytic Diels-Alder-retro-Diels-Alder cascade reaction of ynals with 2-pyrones

Abstract

Keywords

ASJC Scopus subject areas

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