On dielectric saturation modeling in a continuum solvent

Joan E. Curry; Donald A. McQuarrie

doi:10.1016/0021-9797(92)90102-R

On dielectric saturation modeling in a continuum solvent

Joan E. Curry, Donald A. McQuarrie

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

The linear Poisson-Boltzmann equation is solved with a variable dielectric constant to account for dielectric saturation. Two different spatially dependent forms of the dielectric constant are compared. It is shown that the electrostatic repulsion between two flat plates is decreased by dielectric saturation and that it depends in a complicated way on both the dielectric constant and the electric field.

Original language	English (US)
Pages (from-to)	289-294
Number of pages	6
Journal	Journal of Colloid And Interface Science
Volume	154
Issue number	1
DOIs	https://doi.org/10.1016/0021-9797(92)90102-R
State	Published - Nov 1992
Externally published	Yes

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Biomaterials
Surfaces, Coatings and Films
Colloid and Surface Chemistry

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10.1016/0021-9797(92)90102-R

Cite this

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title = "On dielectric saturation modeling in a continuum solvent",

abstract = "The linear Poisson-Boltzmann equation is solved with a variable dielectric constant to account for dielectric saturation. Two different spatially dependent forms of the dielectric constant are compared. It is shown that the electrostatic repulsion between two flat plates is decreased by dielectric saturation and that it depends in a complicated way on both the dielectric constant and the electric field.",

author = "Curry, {Joan E.} and McQuarrie, {Donald A.}",

note = "Funding Information: This work has been supported by the National Science Foundation under Grant NSF EAR 8910530.",

year = "1992",

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doi = "10.1016/0021-9797(92)90102-R",

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AU - McQuarrie, Donald A.

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PY - 1992/11

Y1 - 1992/11

N2 - The linear Poisson-Boltzmann equation is solved with a variable dielectric constant to account for dielectric saturation. Two different spatially dependent forms of the dielectric constant are compared. It is shown that the electrostatic repulsion between two flat plates is decreased by dielectric saturation and that it depends in a complicated way on both the dielectric constant and the electric field.

AB - The linear Poisson-Boltzmann equation is solved with a variable dielectric constant to account for dielectric saturation. Two different spatially dependent forms of the dielectric constant are compared. It is shown that the electrostatic repulsion between two flat plates is decreased by dielectric saturation and that it depends in a complicated way on both the dielectric constant and the electric field.

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U2 - 10.1016/0021-9797(92)90102-R

DO - 10.1016/0021-9797(92)90102-R

M3 - Article

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JO - Journal of Colloid And Interface Science

JF - Journal of Colloid And Interface Science

IS - 1

ER -

On dielectric saturation modeling in a continuum solvent

Abstract

ASJC Scopus subject areas

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