Novel functionalized oligo-vinylthiophene molecules with modulated second-order nonlinear optical response

D. A. Dos Santos; T. Kogej; J. L. Brédas; C. Boutton; E. Hendrickx; S. Houbrechts; K. Clays; A. Persoons; J. X. Xhang; P. Dubois; R. Jérôme

doi:10.1016/S0022-2860(99)00437-8

Novel functionalized oligo-vinylthiophene molecules with modulated second-order nonlinear optical response

D. A. Dos Santos
, T. Kogej
, J. L. Brédas
, C. Boutton
, E. Hendrickx
, S. Houbrechts
, K. Clays
, A. Persoons
, J. X. Xhang
, P. Dubois
, R. Jérôme

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

We present a joint theoretical and experimental investigation of the second-order nonlinear optical properties of a new kind of active molecule with a triblock structure. The molecular architecture is such that two highly polarizable conjugated segments are separated from each other by a spacer; one of the conjugated segments is end-capped with an electron-donor group, the other one by an acceptor. E-vinylthiophenes are used as the conjugated segments; N,N-dimethylaniline and nitrophenyl are selected as the donor- acceptor pairs, while the spacer consists of a nonconjugated moiety. Several spacers are considered and discussed with respect to their ability to modulate the charge transfer between the donor and acceptor ends. (C) 2000 Elsevier Science B.V.

Original language	English (US)
Pages (from-to)	221-230
Number of pages	10
Journal	Journal of Molecular Structure
Volume	521
Issue number	1-3
DOIs	https://doi.org/10.1016/S0022-2860(99)00437-8
State	Published - Mar 28 2000
Externally published	Yes

Keywords

Functionalized oligo-vinylthiophenes
Hyper-Rayleigh scattering
Quantum- chemical calculations
Second-order polarizability
Spacer-incorporated push-pull molecules

ASJC Scopus subject areas

Analytical Chemistry
Spectroscopy
Organic Chemistry
Inorganic Chemistry

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10.1016/S0022-2860(99)00437-8

Cite this

@article{12cdd49ba1d8465fa672d4ecf181412b,

title = "Novel functionalized oligo-vinylthiophene molecules with modulated second-order nonlinear optical response",

abstract = "We present a joint theoretical and experimental investigation of the second-order nonlinear optical properties of a new kind of active molecule with a triblock structure. The molecular architecture is such that two highly polarizable conjugated segments are separated from each other by a spacer; one of the conjugated segments is end-capped with an electron-donor group, the other one by an acceptor. E-vinylthiophenes are used as the conjugated segments; N,N-dimethylaniline and nitrophenyl are selected as the donor- acceptor pairs, while the spacer consists of a nonconjugated moiety. Several spacers are considered and discussed with respect to their ability to modulate the charge transfer between the donor and acceptor ends. (C) 2000 Elsevier Science B.V.",

keywords = "Functionalized oligo-vinylthiophenes, Hyper-Rayleigh scattering, Quantum- chemical calculations, Second-order polarizability, Spacer-incorporated push-pull molecules",

author = "\{Dos Santos\}, \{D. A.\} and T. Kogej and Br{\'e}das, \{J. L.\} and C. Boutton and E. Hendrickx and S. Houbrechts and K. Clays and A. Persoons and Xhang, \{J. X.\} and P. Dubois and R. J{\'e}r{\^o}me",

note = "Funding Information: The authors would like to seize this opportunity to thank warmly Professor Giuseppe Zerbi for many stimulating discussions and for his never-tiring enthusiasm. The Mons-Li{\`e}ge-Leuven collaboration is conducted in the framework of the Belgian Federal Government Services of Scientific, Technical, and Cultural Affairs “P{\^o}le d'Attraction Interuniversitaire en Chimie Supramol{\'e}culaire et Catalyse”. Thierry Kogej is holder of a FRIA fellowship. Eric Hendrickx and Stephan Houbrechts are Research Assistants and Koen Clays is Senior Research Associate of the Fund for Scientific Research—Flanders (FWO-V). This research in Leuven was supported by research grants from the FWO-V (FWO-V G.0338.98 and G.0407.98) and the University of Leuven (GOA/95/01) and that in Mons by the Belgian National Fund for Scientific Research FNRS-FRFC. ",

year = "2000",

month = mar,

day = "28",

doi = "10.1016/S0022-2860(99)00437-8",

language = "English (US)",

volume = "521",

pages = "221--230",

journal = "Journal of Molecular Structure",

issn = "0022-2860",

publisher = "Elsevier B.V.",

number = "1-3",

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TY - JOUR

T1 - Novel functionalized oligo-vinylthiophene molecules with modulated second-order nonlinear optical response

AU - Dos Santos, D. A.

AU - Kogej, T.

AU - Brédas, J. L.

AU - Boutton, C.

AU - Hendrickx, E.

AU - Houbrechts, S.

AU - Clays, K.

AU - Persoons, A.

AU - Xhang, J. X.

AU - Dubois, P.

AU - Jérôme, R.

N1 - Funding Information: The authors would like to seize this opportunity to thank warmly Professor Giuseppe Zerbi for many stimulating discussions and for his never-tiring enthusiasm. The Mons-Liège-Leuven collaboration is conducted in the framework of the Belgian Federal Government Services of Scientific, Technical, and Cultural Affairs “Pôle d'Attraction Interuniversitaire en Chimie Supramoléculaire et Catalyse”. Thierry Kogej is holder of a FRIA fellowship. Eric Hendrickx and Stephan Houbrechts are Research Assistants and Koen Clays is Senior Research Associate of the Fund for Scientific Research—Flanders (FWO-V). This research in Leuven was supported by research grants from the FWO-V (FWO-V G.0338.98 and G.0407.98) and the University of Leuven (GOA/95/01) and that in Mons by the Belgian National Fund for Scientific Research FNRS-FRFC.

PY - 2000/3/28

Y1 - 2000/3/28

N2 - We present a joint theoretical and experimental investigation of the second-order nonlinear optical properties of a new kind of active molecule with a triblock structure. The molecular architecture is such that two highly polarizable conjugated segments are separated from each other by a spacer; one of the conjugated segments is end-capped with an electron-donor group, the other one by an acceptor. E-vinylthiophenes are used as the conjugated segments; N,N-dimethylaniline and nitrophenyl are selected as the donor- acceptor pairs, while the spacer consists of a nonconjugated moiety. Several spacers are considered and discussed with respect to their ability to modulate the charge transfer between the donor and acceptor ends. (C) 2000 Elsevier Science B.V.

AB - We present a joint theoretical and experimental investigation of the second-order nonlinear optical properties of a new kind of active molecule with a triblock structure. The molecular architecture is such that two highly polarizable conjugated segments are separated from each other by a spacer; one of the conjugated segments is end-capped with an electron-donor group, the other one by an acceptor. E-vinylthiophenes are used as the conjugated segments; N,N-dimethylaniline and nitrophenyl are selected as the donor- acceptor pairs, while the spacer consists of a nonconjugated moiety. Several spacers are considered and discussed with respect to their ability to modulate the charge transfer between the donor and acceptor ends. (C) 2000 Elsevier Science B.V.

KW - Functionalized oligo-vinylthiophenes

KW - Hyper-Rayleigh scattering

KW - Quantum- chemical calculations

KW - Second-order polarizability

KW - Spacer-incorporated push-pull molecules

UR - https://www.scopus.com/pages/publications/0034724130

UR - https://www.scopus.com/pages/publications/0034724130#tab=citedBy

U2 - 10.1016/S0022-2860(99)00437-8

DO - 10.1016/S0022-2860(99)00437-8

M3 - Article

AN - SCOPUS:0034724130

SN - 0022-2860

VL - 521

SP - 221

EP - 230

JO - Journal of Molecular Structure

JF - Journal of Molecular Structure

IS - 1-3

ER -

Novel functionalized oligo-vinylthiophene molecules with modulated second-order nonlinear optical response

Abstract

Keywords

ASJC Scopus subject areas

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