Nonexistent electron affinity of OCS and the stabilization of carbonyl sulfide anions by gas phase hydration

Eric Surber; S. P. Ananthavel; Andrei Sanov

doi:10.1063/1.1433001

Nonexistent electron affinity of OCS and the stabilization of carbonyl sulfide anions by gas phase hydration

Eric Surber, S. P. Ananthavel, Andrei Sanov

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Abstract

The formation of the [(OCS)_n(H₂O)_k]^-- (n≥1,n+k≥2) cluster ions was followed. OCS^-·H₂O was found to be the most interesting species in view of the near absence of the seemingly simpler OCS^- in the same ion source. The presence of the monohydrated anions was attribued to the stabilization of OCS^- by hydration and served as unambiguous proof that the intra-cluster formation of OCS^- monomers is part of the [(OCS)_n(H₂O)_k]^- dynamics.

Original language	English (US)
Pages (from-to)	1920-1929
Number of pages	10
Journal	Journal of Chemical Physics
Volume	116
Issue number	5
DOIs	https://doi.org/10.1063/1.1433001
State	Published - Feb 1 2002

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Physics and Astronomy(all)
Physical and Theoretical Chemistry

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title = "Nonexistent electron affinity of OCS and the stabilization of carbonyl sulfide anions by gas phase hydration",

abstract = "The formation of the [(OCS)n(H2O)k]-- (n≥1,n+k≥2) cluster ions was followed. OCS-·H2O was found to be the most interesting species in view of the near absence of the seemingly simpler OCS- in the same ion source. The presence of the monohydrated anions was attribued to the stabilization of OCS- by hydration and served as unambiguous proof that the intra-cluster formation of OCS- monomers is part of the [(OCS)n(H2O)k]- dynamics.",

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T1 - Nonexistent electron affinity of OCS and the stabilization of carbonyl sulfide anions by gas phase hydration

AU - Surber, Eric

AU - Ananthavel, S. P.

AU - Sanov, Andrei

PY - 2002/2/1

Y1 - 2002/2/1

N2 - The formation of the [(OCS)n(H2O)k]-- (n≥1,n+k≥2) cluster ions was followed. OCS-·H2O was found to be the most interesting species in view of the near absence of the seemingly simpler OCS- in the same ion source. The presence of the monohydrated anions was attribued to the stabilization of OCS- by hydration and served as unambiguous proof that the intra-cluster formation of OCS- monomers is part of the [(OCS)n(H2O)k]- dynamics.

AB - The formation of the [(OCS)n(H2O)k]-- (n≥1,n+k≥2) cluster ions was followed. OCS-·H2O was found to be the most interesting species in view of the near absence of the seemingly simpler OCS- in the same ion source. The presence of the monohydrated anions was attribued to the stabilization of OCS- by hydration and served as unambiguous proof that the intra-cluster formation of OCS- monomers is part of the [(OCS)n(H2O)k]- dynamics.

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JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

IS - 5

ER -

Nonexistent electron affinity of OCS and the stabilization of carbonyl sulfide anions by gas phase hydration

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