Nitrogen Quadrupole Coupling in Cyclopentadienylnickel Nitrosyl

S. G. Kukolich; J. V. Rund; D. J. Pauley; R. E. Bumgarner

doi:10.1021/ja00230a015

Nitrogen Quadrupole Coupling in Cyclopentadienylnickel Nitrosyl

S. G. Kukolich, J. V. Rund, D. J. Pauley, R. E. Bumgarner

Chemistry and Biochemistry

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

High-resolution rotational spectra of C₅H₅⁵⁸Ni^l4N¹⁶O were obtained with a Flygare-Balle type pulsed-beam microwave spectrometer. Quadrupole hyperfine structure was clearly resolved for J = 1 → 2, 2 → 3, 3→ 4, and 4 → 5 transitions involving K = 0, 1, 2, 3, and 4 states. A nitrogen quadrupole coupling strength of eqQ = —1.216 (11) MHz and rotational constant B = 1259.2743 (8) MHz were obtained by fitting the observed spectra. D_JKand Dj were also obtained from fitting the spectra. This appears to be the first gas-phase, microwave measurement of nitrogen quadrupole coupling in a transition-metal complex. The quadrupole coupling strength is compared with values for other molecules and complexes containing the NO group.

Original language	English (US)
Pages (from-to)	7356-7357
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	110
Issue number	22
DOIs	https://doi.org/10.1021/ja00230a015
State	Published - Oct 1988

ASJC Scopus subject areas

Catalysis
General Chemistry
Biochemistry
Colloid and Surface Chemistry

Access to Document

10.1021/ja00230a015

Cite this

@article{3f0df266dfde4e3a8b2fb98d71a8d172,

title = "Nitrogen Quadrupole Coupling in Cyclopentadienylnickel Nitrosyl",

abstract = "High-resolution rotational spectra of C5H558Nil4N16O were obtained with a Flygare-Balle type pulsed-beam microwave spectrometer. Quadrupole hyperfine structure was clearly resolved for J = 1 → 2, 2 → 3, 3→ 4, and 4 → 5 transitions involving K = 0, 1, 2, 3, and 4 states. A nitrogen quadrupole coupling strength of eqQ = —1.216 (11) MHz and rotational constant B = 1259.2743 (8) MHz were obtained by fitting the observed spectra. DJKand Dj were also obtained from fitting the spectra. This appears to be the first gas-phase, microwave measurement of nitrogen quadrupole coupling in a transition-metal complex. The quadrupole coupling strength is compared with values for other molecules and complexes containing the NO group.",

author = "Kukolich, {S. G.} and Rund, {J. V.} and Pauley, {D. J.} and Bumgarner, {R. E.}",

year = "1988",

month = oct,

doi = "10.1021/ja00230a015",

language = "English (US)",

volume = "110",

pages = "7356--7357",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

publisher = "American Chemical Society",

number = "22",

}

TY - JOUR

T1 - Nitrogen Quadrupole Coupling in Cyclopentadienylnickel Nitrosyl

AU - Kukolich, S. G.

AU - Rund, J. V.

AU - Pauley, D. J.

AU - Bumgarner, R. E.

PY - 1988/10

Y1 - 1988/10

N2 - High-resolution rotational spectra of C5H558Nil4N16O were obtained with a Flygare-Balle type pulsed-beam microwave spectrometer. Quadrupole hyperfine structure was clearly resolved for J = 1 → 2, 2 → 3, 3→ 4, and 4 → 5 transitions involving K = 0, 1, 2, 3, and 4 states. A nitrogen quadrupole coupling strength of eqQ = —1.216 (11) MHz and rotational constant B = 1259.2743 (8) MHz were obtained by fitting the observed spectra. DJKand Dj were also obtained from fitting the spectra. This appears to be the first gas-phase, microwave measurement of nitrogen quadrupole coupling in a transition-metal complex. The quadrupole coupling strength is compared with values for other molecules and complexes containing the NO group.

AB - High-resolution rotational spectra of C5H558Nil4N16O were obtained with a Flygare-Balle type pulsed-beam microwave spectrometer. Quadrupole hyperfine structure was clearly resolved for J = 1 → 2, 2 → 3, 3→ 4, and 4 → 5 transitions involving K = 0, 1, 2, 3, and 4 states. A nitrogen quadrupole coupling strength of eqQ = —1.216 (11) MHz and rotational constant B = 1259.2743 (8) MHz were obtained by fitting the observed spectra. DJKand Dj were also obtained from fitting the spectra. This appears to be the first gas-phase, microwave measurement of nitrogen quadrupole coupling in a transition-metal complex. The quadrupole coupling strength is compared with values for other molecules and complexes containing the NO group.

UR - http://www.scopus.com/inward/record.url?scp=33845279842&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=33845279842&partnerID=8YFLogxK

U2 - 10.1021/ja00230a015

DO - 10.1021/ja00230a015

M3 - Article

AN - SCOPUS:33845279842

SN - 0002-7863

VL - 110

SP - 7356

EP - 7357

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 22

ER -

Nitrogen Quadrupole Coupling in Cyclopentadienylnickel Nitrosyl

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this