Nitrogen quadrupole coupling and spin-rotation interaction in CH3NC

S. G. Kukolich

doi:10.1016/0009-2614(71)80154-9

Nitrogen quadrupole coupling and spin-rotation interaction in CH₃NC

S. G. Kukolich

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

Hyperfine structure on the J = 1→0 transition in CH₃NC was observed using a molecular beam maser spectrometer with 6 kHz resolution. Molecular parameters obtained from an analysis of the spectrum are: the nitrogen quadrupole coupling strength eqQ = (488.5±1.0) kHz, the nitrogen spin-rotation strength C_N = (1.45±0.5) kHz, the hydrogen-hydrogen spin-spin interaction strength D_HH = (21.33±0.5) kHz and the hydrogen spin-rotation strength C_H = (-0.3±0.5) kHz.

Original language	English (US)
Pages (from-to)	52-55
Number of pages	4
Journal	Chemical Physics Letters
Volume	10
Issue number	1
DOIs	https://doi.org/10.1016/0009-2614(71)80154-9
State	Published - Jul 1 1971
Externally published	Yes

ASJC Scopus subject areas

General Physics and Astronomy
Physical and Theoretical Chemistry

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10.1016/0009-2614(71)80154-9

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title = "Nitrogen quadrupole coupling and spin-rotation interaction in CH3NC",

abstract = "Hyperfine structure on the J = 1→0 transition in CH3NC was observed using a molecular beam maser spectrometer with 6 kHz resolution. Molecular parameters obtained from an analysis of the spectrum are: the nitrogen quadrupole coupling strength eqQ = (488.5±1.0) kHz, the nitrogen spin-rotation strength CN = (1.45±0.5) kHz, the hydrogen-hydrogen spin-spin interaction strength DHH = (21.33±0.5) kHz and the hydrogen spin-rotation strength CH = (-0.3±0.5) kHz.",

author = "Kukolich, {S. G.}",

year = "1971",

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doi = "10.1016/0009-2614(71)80154-9",

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T1 - Nitrogen quadrupole coupling and spin-rotation interaction in CH3NC

AU - Kukolich, S. G.

PY - 1971/7/1

Y1 - 1971/7/1

N2 - Hyperfine structure on the J = 1→0 transition in CH3NC was observed using a molecular beam maser spectrometer with 6 kHz resolution. Molecular parameters obtained from an analysis of the spectrum are: the nitrogen quadrupole coupling strength eqQ = (488.5±1.0) kHz, the nitrogen spin-rotation strength CN = (1.45±0.5) kHz, the hydrogen-hydrogen spin-spin interaction strength DHH = (21.33±0.5) kHz and the hydrogen spin-rotation strength CH = (-0.3±0.5) kHz.

AB - Hyperfine structure on the J = 1→0 transition in CH3NC was observed using a molecular beam maser spectrometer with 6 kHz resolution. Molecular parameters obtained from an analysis of the spectrum are: the nitrogen quadrupole coupling strength eqQ = (488.5±1.0) kHz, the nitrogen spin-rotation strength CN = (1.45±0.5) kHz, the hydrogen-hydrogen spin-spin interaction strength DHH = (21.33±0.5) kHz and the hydrogen spin-rotation strength CH = (-0.3±0.5) kHz.

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JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 1

ER -

Nitrogen quadrupole coupling and spin-rotation interaction in CH₃NC

Abstract

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