NiMoO4 selective oxidation catalysts containing excess MoO3 for the conversion of C4 hydrocarbons to maleic anhydride. III. Selective oxidation of 1,3-butadiene and furan

U. Ozkan; G. L. Schrader

doi:10.1016/0021-9517(85)90015-6

NiMoO₄ selective oxidation catalysts containing excess MoO₃ for the conversion of C₄ hydrocarbons to maleic anhydride. III. Selective oxidation of 1,3-butadiene and furan

U. Ozkan, G. L. Schrader

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Abstract

The selective oxidation of 1,3-butadiene and furan to maleic anhydride over NiMoO₄ catalysts containing excess MoO₃ was investigated. Activity and selectivity measurements were performed using a fixed-bed, integral reactor system. The results were compared with those obtained for 1-butene oxidation which indicated the most selective component of the catalyst for maleic anhydride formation was a MoO₃ phase having a surface covering of NiMoO₄; similar results were found to be applicable for 1,3-butadiene and furan oxidation. NiMoO₄4 was determined to be the catalyst component responsible for oxidative dehydrogenation of 1-butene; this phase also selectively blocked complete oxidation sites on MoO₃, thereby changing the selectivity in favor of maleic anhydride.

Original language	English (US)
Pages (from-to)	147-154
Number of pages	8
Journal	Journal of Catalysis
Volume	95
Issue number	1
DOIs	https://doi.org/10.1016/0021-9517(85)90015-6
State	Published - Sep 1985
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Physical and Theoretical Chemistry

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10.1016/0021-9517(85)90015-6

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title = "NiMoO4 selective oxidation catalysts containing excess MoO3 for the conversion of C4 hydrocarbons to maleic anhydride. III. Selective oxidation of 1,3-butadiene and furan",

abstract = "The selective oxidation of 1,3-butadiene and furan to maleic anhydride over NiMoO4 catalysts containing excess MoO3 was investigated. Activity and selectivity measurements were performed using a fixed-bed, integral reactor system. The results were compared with those obtained for 1-butene oxidation which indicated the most selective component of the catalyst for maleic anhydride formation was a MoO3 phase having a surface covering of NiMoO4; similar results were found to be applicable for 1,3-butadiene and furan oxidation. NiMoO44 was determined to be the catalyst component responsible for oxidative dehydrogenation of 1-butene; this phase also selectively blocked complete oxidation sites on MoO3, thereby changing the selectivity in favor of maleic anhydride.",

author = "U. Ozkan and Schrader, {G. L.}",

note = "Funding Information: This work was conductedt hrought he Ames Laboratory which is operated for the U.S. Departmento f Energy by Iowa State University under Contract W-7405Eng-82.T his researchw as supportedb y the Office of Basic Energy Sciences, Chemical Sciences Division.",

year = "1985",

month = sep,

doi = "10.1016/0021-9517(85)90015-6",

language = "English (US)",

volume = "95",

pages = "147--154",

journal = "Journal of Catalysis",

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publisher = "Academic Press Inc.",

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T1 - NiMoO4 selective oxidation catalysts containing excess MoO3 for the conversion of C4 hydrocarbons to maleic anhydride. III. Selective oxidation of 1,3-butadiene and furan

AU - Ozkan, U.

AU - Schrader, G. L.

N1 - Funding Information: This work was conductedt hrought he Ames Laboratory which is operated for the U.S. Departmento f Energy by Iowa State University under Contract W-7405Eng-82.T his researchw as supportedb y the Office of Basic Energy Sciences, Chemical Sciences Division.

PY - 1985/9

Y1 - 1985/9

N2 - The selective oxidation of 1,3-butadiene and furan to maleic anhydride over NiMoO4 catalysts containing excess MoO3 was investigated. Activity and selectivity measurements were performed using a fixed-bed, integral reactor system. The results were compared with those obtained for 1-butene oxidation which indicated the most selective component of the catalyst for maleic anhydride formation was a MoO3 phase having a surface covering of NiMoO4; similar results were found to be applicable for 1,3-butadiene and furan oxidation. NiMoO44 was determined to be the catalyst component responsible for oxidative dehydrogenation of 1-butene; this phase also selectively blocked complete oxidation sites on MoO3, thereby changing the selectivity in favor of maleic anhydride.

AB - The selective oxidation of 1,3-butadiene and furan to maleic anhydride over NiMoO4 catalysts containing excess MoO3 was investigated. Activity and selectivity measurements were performed using a fixed-bed, integral reactor system. The results were compared with those obtained for 1-butene oxidation which indicated the most selective component of the catalyst for maleic anhydride formation was a MoO3 phase having a surface covering of NiMoO4; similar results were found to be applicable for 1,3-butadiene and furan oxidation. NiMoO44 was determined to be the catalyst component responsible for oxidative dehydrogenation of 1-butene; this phase also selectively blocked complete oxidation sites on MoO3, thereby changing the selectivity in favor of maleic anhydride.

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NiMoO₄ selective oxidation catalysts containing excess MoO₃ for the conversion of C₄ hydrocarbons to maleic anhydride. III. Selective oxidation of 1,3-butadiene and furan

Abstract

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