TY - JOUR
T1 - New trialkylsilyl enol ether chemistry
T2 - Direct 1,2-bis-azidonation of triisopropylsilyl enol ethers: An azido-radical addition process promoted by TEMPO
AU - Magnus, Philip
AU - Roe, Michael B.
AU - Hulme, Christopher
PY - 1995
Y1 - 1995
N2 - Treatment of triisopropylsilyl enol ethers with PhIO/TMSN3/TEMPO (cat.) -45°C results in 1,2-bis-azidonation, which appears to occur through a radical addition process; the 1-azido group can be replaced by carbon nucleophiles such as allyl, methyl, cyano, acetylene and acetonyl.
AB - Treatment of triisopropylsilyl enol ethers with PhIO/TMSN3/TEMPO (cat.) -45°C results in 1,2-bis-azidonation, which appears to occur through a radical addition process; the 1-azido group can be replaced by carbon nucleophiles such as allyl, methyl, cyano, acetylene and acetonyl.
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U2 - 10.1039/C39950000263
DO - 10.1039/C39950000263
M3 - Article
AN - SCOPUS:37049090118
SN - 0022-4936
SP - 263
EP - 265
JO - Journal of the Chemical Society, Chemical Communications
JF - Journal of the Chemical Society, Chemical Communications
IS - 2
ER -