Molybdate templated assembly of ln12mo4-type clusters (ln = sm, eu, gd) containing a truncated tetrahedron core

Yong Zheng; Qian Chong Zhang; La Sheng Long; Rong Bin Huang; Achim Müller; Jürgen Schnack; Lan Sun Zheng; Zhiping Zheng

doi:10.1039/c2cc36530h

Molybdate templated assembly of ln₁₂mo₄-type clusters (ln = sm, eu, gd) containing a truncated tetrahedron core

Yong Zheng
, Qian Chong Zhang
, La Sheng Long
, Rong Bin Huang
, Achim Müller
, Jürgen Schnack
, Lan Sun Zheng
, Zhiping Zheng

Research output: Contribution to journal › Article › peer-review

72 Scopus citations

Abstract

Three heterometallic cluster complexes {Ln₁₂Mo₄} featuring an Ln₁₂ core of a distorted truncated tetrahedron were synthesized with the assistance of four MoO₄²⁻ anions as ancillary ligands. Magnetic studies of the {Gd₁₂Mo₄} cluster revealed a large magnetocaloric effect due to the presence of the large number of weakly coupled Gd(iii) ions.

Original language	English (US)
Pages (from-to)	36-38
Number of pages	3
Journal	Chemical Communications
Volume	49
Issue number	1
DOIs	https://doi.org/10.1039/c2cc36530h
State	Published - 2013
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/c2cc36530h

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title = "Molybdate templated assembly of ln12mo4-type clusters (ln = sm, eu, gd) containing a truncated tetrahedron core",

abstract = "Three heterometallic cluster complexes \{Ln12Mo4\} featuring an Ln12 core of a distorted truncated tetrahedron were synthesized with the assistance of four MoO42− anions as ancillary ligands. Magnetic studies of the \{Gd12Mo4\} cluster revealed a large magnetocaloric effect due to the presence of the large number of weakly coupled Gd(iii) ions.",

author = "Yong Zheng and Zhang, \{Qian Chong\} and Long, \{La Sheng\} and Huang, \{Rong Bin\} and Achim M{\"u}ller and J{\"u}rgen Schnack and Zheng, \{Lan Sun\} and Zhiping Zheng",

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doi = "10.1039/c2cc36530h",

language = "English (US)",

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T1 - Molybdate templated assembly of ln12mo4-type clusters (ln = sm, eu, gd) containing a truncated tetrahedron core

AU - Zheng, Yong

AU - Zhang, Qian Chong

AU - Long, La Sheng

AU - Huang, Rong Bin

AU - Müller, Achim

AU - Schnack, Jürgen

AU - Zheng, Lan Sun

AU - Zheng, Zhiping

PY - 2013

Y1 - 2013

N2 - Three heterometallic cluster complexes {Ln12Mo4} featuring an Ln12 core of a distorted truncated tetrahedron were synthesized with the assistance of four MoO42− anions as ancillary ligands. Magnetic studies of the {Gd12Mo4} cluster revealed a large magnetocaloric effect due to the presence of the large number of weakly coupled Gd(iii) ions.

AB - Three heterometallic cluster complexes {Ln12Mo4} featuring an Ln12 core of a distorted truncated tetrahedron were synthesized with the assistance of four MoO42− anions as ancillary ligands. Magnetic studies of the {Gd12Mo4} cluster revealed a large magnetocaloric effect due to the presence of the large number of weakly coupled Gd(iii) ions.

UR - https://www.scopus.com/pages/publications/84870202744

UR - https://www.scopus.com/pages/publications/84870202744#tab=citedBy

U2 - 10.1039/c2cc36530h

DO - 10.1039/c2cc36530h

M3 - Article

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AN - SCOPUS:84870202744

SN - 1359-7345

VL - 49

SP - 36

EP - 38

JO - Chemical Communications

JF - Chemical Communications

IS - 1

ER -

Molybdate templated assembly of ln₁₂mo₄-type clusters (ln = sm, eu, gd) containing a truncated tetrahedron core

Abstract

ASJC Scopus subject areas

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