Molecules in high spin states: The millimeter and submillimeter spectrum of the MnS radical (X 6Σ+)

J. M. Thompsen; M. A. Brewster; L. M. Ziurys

doi:10.1063/1.1476931

Molecules in high spin states: The millimeter and submillimeter spectrum of the MnS radical (X ⁶Σ⁺)

J. M. Thompsen, M. A. Brewster, L. M. Ziurys

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Abstract

The pure rotational spectrum of MnS (v = 0) in its X⁶σ⁺ ground state was discussed using millimeter and submillimeter direct absorption techniques. MnS was synthesized in the gas phase by the reaction of manganese vapor and CS₂ in a high-temperature Borida-type oven and fourteen rotational transitions were measured for this radical. The analysis showed that MnS was more covalent than MnO but more ionic than MnH.

Original language	English (US)
Pages (from-to)	10212-10220
Number of pages	9
Journal	Journal of Chemical Physics
Volume	116
Issue number	23
DOIs	https://doi.org/10.1063/1.1476931
State	Published - Jun 23 2002

ASJC Scopus subject areas

General Physics and Astronomy
Physical and Theoretical Chemistry

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abstract = "The pure rotational spectrum of MnS (v = 0) in its X6σ+ ground state was discussed using millimeter and submillimeter direct absorption techniques. MnS was synthesized in the gas phase by the reaction of manganese vapor and CS2 in a high-temperature Borida-type oven and fourteen rotational transitions were measured for this radical. The analysis showed that MnS was more covalent than MnO but more ionic than MnH.",

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AB - The pure rotational spectrum of MnS (v = 0) in its X6σ+ ground state was discussed using millimeter and submillimeter direct absorption techniques. MnS was synthesized in the gas phase by the reaction of manganese vapor and CS2 in a high-temperature Borida-type oven and fourteen rotational transitions were measured for this radical. The analysis showed that MnS was more covalent than MnO but more ionic than MnH.

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Molecules in high spin states: The millimeter and submillimeter spectrum of the MnS radical (X ⁶Σ⁺)

Abstract

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