Abstract
The J = 1 → 0 transition in CF3H and CF3D was observed using a molecular beam maser spectrometer. Typical resonance linewidths were 6 kHz (F.W.H.M.). Hyperfine structure due to deuterium quadrupole coupling, spinrotation and spin-spin interactions was resolved. The strength of the deuterium quadrupole coupling along the bond axis is eqQ = 170.8 ± 2.0 kHz. Fluorine and hydrogen spin-rotation interaction strengths were obtained.
Original language | English (US) |
---|---|
Pages (from-to) | 33-39 |
Number of pages | 7 |
Journal | Journal of Molecular Spectroscopy |
Volume | 40 |
Issue number | 1 |
DOIs | |
State | Published - Oct 1971 |
Externally published | Yes |
ASJC Scopus subject areas
- Atomic and Molecular Physics, and Optics
- Spectroscopy
- Physical and Theoretical Chemistry