Microwave structure determination and quadrupole coupling measurements on acetylene-HCN and ethylene-HCN complexes

S. G. Kukolich; P. D. Aldrich; W. G. Read; E. J. Cambell

doi:10.1016/0009-2614(82)83062-5

Microwave structure determination and quadrupole coupling measurements on acetylene-HCN and ethylene-HCN complexes

S. G. Kukolich, P. D. Aldrich, W. G. Read, E. J. Cambell

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Abstract

Microwave rotational spectra for the complexes HCCH-HCN, HCCH-DCN, DCCD-HCN, H₂CCh₂-HCN and H₂CCH₂-DCN were observed using a pulsed nozzle Fourier transform spectrometer. The distance from the HCN carbon atom the the center of mass is. 3.655(10) Å for acetylene-HCN and 3.709(10) Å for ethylene-HCN. Both complex are T-shaped with the HCN hydrogen atom closest to the CC bond. The HCN axis is perpendicular to the plane of ethylene for ethylene-HCN. Nitrogen and deuterium quadrupole coupling was measured.

Original language	English (US)
Pages (from-to)	329-331
Number of pages	3
Journal	Chemical Physics Letters
Volume	90
Issue number	5
DOIs	https://doi.org/10.1016/0009-2614(82)83062-5
State	Published - Aug 13 1982
Externally published	Yes

ASJC Scopus subject areas

General Physics and Astronomy
Physical and Theoretical Chemistry

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@article{703159b989ef41b9a025f227b423af3e,

title = "Microwave structure determination and quadrupole coupling measurements on acetylene-HCN and ethylene-HCN complexes",

abstract = "Microwave rotational spectra for the complexes HCCH-HCN, HCCH-DCN, DCCD-HCN, H2CCh2-HCN and H2CCH2-DCN were observed using a pulsed nozzle Fourier transform spectrometer. The distance from the HCN carbon atom the the center of mass is. 3.655(10) {\AA} for acetylene-HCN and 3.709(10) {\AA} for ethylene-HCN. Both complex are T-shaped with the HCN hydrogen atom closest to the CC bond. The HCN axis is perpendicular to the plane of ethylene for ethylene-HCN. Nitrogen and deuterium quadrupole coupling was measured.",

author = "Kukolich, {S. G.} and Aldrich, {P. D.} and Read, {W. G.} and Cambell, {E. J.}",

year = "1982",

month = aug,

day = "13",

doi = "10.1016/0009-2614(82)83062-5",

language = "English (US)",

volume = "90",

pages = "329--331",

journal = "Chemical Physics Letters",

issn = "0009-2614",

publisher = "Elsevier B.V.",

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}

TY - JOUR

T1 - Microwave structure determination and quadrupole coupling measurements on acetylene-HCN and ethylene-HCN complexes

AU - Kukolich, S. G.

AU - Aldrich, P. D.

AU - Read, W. G.

AU - Cambell, E. J.

PY - 1982/8/13

Y1 - 1982/8/13

N2 - Microwave rotational spectra for the complexes HCCH-HCN, HCCH-DCN, DCCD-HCN, H2CCh2-HCN and H2CCH2-DCN were observed using a pulsed nozzle Fourier transform spectrometer. The distance from the HCN carbon atom the the center of mass is. 3.655(10) Å for acetylene-HCN and 3.709(10) Å for ethylene-HCN. Both complex are T-shaped with the HCN hydrogen atom closest to the CC bond. The HCN axis is perpendicular to the plane of ethylene for ethylene-HCN. Nitrogen and deuterium quadrupole coupling was measured.

AB - Microwave rotational spectra for the complexes HCCH-HCN, HCCH-DCN, DCCD-HCN, H2CCh2-HCN and H2CCH2-DCN were observed using a pulsed nozzle Fourier transform spectrometer. The distance from the HCN carbon atom the the center of mass is. 3.655(10) Å for acetylene-HCN and 3.709(10) Å for ethylene-HCN. Both complex are T-shaped with the HCN hydrogen atom closest to the CC bond. The HCN axis is perpendicular to the plane of ethylene for ethylene-HCN. Nitrogen and deuterium quadrupole coupling was measured.

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U2 - 10.1016/0009-2614(82)83062-5

DO - 10.1016/0009-2614(82)83062-5

M3 - Article

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SN - 0009-2614

VL - 90

SP - 329

EP - 331

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 5

ER -

Microwave structure determination and quadrupole coupling measurements on acetylene-HCN and ethylene-HCN complexes

Abstract

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