Microwave spectrum of the SO2-H2S complex

D. J. Pauley; R. E. Bumgarner; S. G. Kukolich

doi:10.1016/0009-2614(86)80696-0

Microwave spectrum of the SO₂-H₂S complex

D. J. Pauley, R. E. Bumgarner, S. G. Kukolich

Chemistry and Biochemistry

Research output: Contribution to journal › Article › peer-review

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Abstract

Ten ΔJ= 1 rotational transitions for the SO₂-H₂S complex were observed in the 4-12 GHz frequency range using a pulsed-beam Fourier-transform microwave spectrometer. The complex is a near-prolate asymmetric top with 1 2(B + C) = 1649(6) MHz and B - C = 228(10) MHz. Some of the observed transitions show inversion or hindered internal rotation splittings. A tentative structure is a non-planar cyclic complex containing two hydrogen bonds from H₂S to the oxygen atoms on SO₂.

Original language	English (US)
Pages (from-to)	67-68
Number of pages	2
Journal	Chemical Physics Letters
Volume	132
Issue number	1
DOIs	https://doi.org/10.1016/0009-2614(86)80696-0
State	Published - Nov 28 1986

ASJC Scopus subject areas

General Physics and Astronomy
Physical and Theoretical Chemistry

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title = "Microwave spectrum of the SO2-H2S complex",

abstract = "Ten ΔJ= 1 rotational transitions for the SO2-H2S complex were observed in the 4-12 GHz frequency range using a pulsed-beam Fourier-transform microwave spectrometer. The complex is a near-prolate asymmetric top with 1 2(B + C) = 1649(6) MHz and B - C = 228(10) MHz. Some of the observed transitions show inversion or hindered internal rotation splittings. A tentative structure is a non-planar cyclic complex containing two hydrogen bonds from H2S to the oxygen atoms on SO2.",

author = "Pauley, {D. J.} and Bumgarner, {R. E.} and Kukolich, {S. G.}",

note = "Funding Information: This work wass upportedb y the NationalS cience FoundationA. cknowledgemeinst m adet o thed onors of theP etroleumR esearchF und,a dministerebdy the AmericanC hemicaSl ocietyf or partials upporot f this researchW. e thank Brian Arnold, SameerS rivas-tava,D on Finch, and Ron Claytonf or help in con-structingth ea pparatus.",

year = "1986",

month = nov,

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doi = "10.1016/0009-2614(86)80696-0",

language = "English (US)",

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T1 - Microwave spectrum of the SO2-H2S complex

AU - Pauley, D. J.

AU - Bumgarner, R. E.

AU - Kukolich, S. G.

N1 - Funding Information: This work wass upportedb y the NationalS cience FoundationA. cknowledgemeinst m adet o thed onors of theP etroleumR esearchF und,a dministerebdy the AmericanC hemicaSl ocietyf or partials upporot f this researchW. e thank Brian Arnold, SameerS rivas-tava,D on Finch, and Ron Claytonf or help in con-structingth ea pparatus.

PY - 1986/11/28

Y1 - 1986/11/28

N2 - Ten ΔJ= 1 rotational transitions for the SO2-H2S complex were observed in the 4-12 GHz frequency range using a pulsed-beam Fourier-transform microwave spectrometer. The complex is a near-prolate asymmetric top with 1 2(B + C) = 1649(6) MHz and B - C = 228(10) MHz. Some of the observed transitions show inversion or hindered internal rotation splittings. A tentative structure is a non-planar cyclic complex containing two hydrogen bonds from H2S to the oxygen atoms on SO2.

AB - Ten ΔJ= 1 rotational transitions for the SO2-H2S complex were observed in the 4-12 GHz frequency range using a pulsed-beam Fourier-transform microwave spectrometer. The complex is a near-prolate asymmetric top with 1 2(B + C) = 1649(6) MHz and B - C = 228(10) MHz. Some of the observed transitions show inversion or hindered internal rotation splittings. A tentative structure is a non-planar cyclic complex containing two hydrogen bonds from H2S to the oxygen atoms on SO2.

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Microwave spectrum of the SO₂-H₂S complex

Abstract

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