The rotational spectra of 14 isotopomers was used to investigate the molecular structure of acetylenemethyldioxorhenium. The catalyzed reactions of methyltrioxorhenium and osmium tetroxide related the complex to its intermediates. Microwave spectrometers of the Flygare-Balle type were used for the structural analysis. The rotational constants were found in correlation with the density functional theory.
ASJC Scopus subject areas
- Physics and Astronomy(all)
- Physical and Theoretical Chemistry