Microwave spectra and the metal-hydrogen bond lengths for the C 5H 5Mo(CO) 3H and C 5H 5W(CO) 3H complexes

Chakree Tanjaroon; Kristen S. Keck; Matthew M. Sebonia; Chandana Karunatilaka; Stephen G. Kukolich

doi:10.1063/1.1764504

Microwave spectra and the metal-hydrogen bond lengths for the C ₅H ₅Mo(CO) ₃H and C ₅H ₅W(CO) ₃H complexes

Chakree Tanjaroon, Kristen S. Keck, Matthew M. Sebonia, Chandana Karunatilaka, Stephen G. Kukolich

Chemistry and Biochemistry

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

The microwave spectra and the metal-hydrogen bond lengths for the C ₅H ₅Mo(CO) ₃H and C ₅H ₅W(CO) ₃H complexes were analyzed. The sample was heated to produce vapor pressure before pulsing of the sample into the microwave cavity. Measurement of rotational frequencies in the range of 4-12 GHz were performed using a pulsed beam fourier transform microwave spectrometer. Result shows that the Mo-H value is in good agreement with the x ray and neutron diffraction studies of similar complexes.

Original language	English (US)
Pages (from-to)	1449-1453
Number of pages	5
Journal	Journal of Chemical Physics
Volume	121
Issue number	3
DOIs	https://doi.org/10.1063/1.1764504
State	Published - Jul 15 2004

ASJC Scopus subject areas

General Physics and Astronomy
Physical and Theoretical Chemistry

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abstract = "The microwave spectra and the metal-hydrogen bond lengths for the C 5H 5Mo(CO) 3H and C 5H 5W(CO) 3H complexes were analyzed. The sample was heated to produce vapor pressure before pulsing of the sample into the microwave cavity. Measurement of rotational frequencies in the range of 4-12 GHz were performed using a pulsed beam fourier transform microwave spectrometer. Result shows that the Mo-H value is in good agreement with the x ray and neutron diffraction studies of similar complexes.",

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T1 - Microwave spectra and the metal-hydrogen bond lengths for the C 5H 5Mo(CO) 3H and C 5H 5W(CO) 3H complexes

AU - Tanjaroon, Chakree

AU - Keck, Kristen S.

AU - Sebonia, Matthew M.

AU - Karunatilaka, Chandana

AU - Kukolich, Stephen G.

PY - 2004/7/15

Y1 - 2004/7/15

N2 - The microwave spectra and the metal-hydrogen bond lengths for the C 5H 5Mo(CO) 3H and C 5H 5W(CO) 3H complexes were analyzed. The sample was heated to produce vapor pressure before pulsing of the sample into the microwave cavity. Measurement of rotational frequencies in the range of 4-12 GHz were performed using a pulsed beam fourier transform microwave spectrometer. Result shows that the Mo-H value is in good agreement with the x ray and neutron diffraction studies of similar complexes.

AB - The microwave spectra and the metal-hydrogen bond lengths for the C 5H 5Mo(CO) 3H and C 5H 5W(CO) 3H complexes were analyzed. The sample was heated to produce vapor pressure before pulsing of the sample into the microwave cavity. Measurement of rotational frequencies in the range of 4-12 GHz were performed using a pulsed beam fourier transform microwave spectrometer. Result shows that the Mo-H value is in good agreement with the x ray and neutron diffraction studies of similar complexes.

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JF - Journal of Chemical Physics

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ER -

Microwave spectra and the metal-hydrogen bond lengths for the C ₅H ₅Mo(CO) ₃H and C ₅H ₅W(CO) ₃H complexes

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