Mechanism of the ring opening of a tetraaryl thiirane cation radical

Richard S. Glass; Woncheol Jung

doi:10.1080/10426509408034261

Mechanism of the ring opening of a tetraaryl thiirane cation radical

Richard S. Glass
, Woncheol Jung

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

The mechanism for the photocycloaddition of tetraarylthiiranes 1 with TCNE was probed by stereochemical and spectroscopic studies. Evidence is presented that the cation radical formed on irradiation of the charge transfer complexes of 1 and TCNE is a p-anisyl π-cation radical which then undergoes stereospecific ring opening by C-C bond cleavage.

Original language	English (US)
Pages (from-to)	423-424
Number of pages	2
Journal	Phosphorus, Sulfur, and Silicon and the Related Elements
Volume	95
Issue number	1-4
DOIs	https://doi.org/10.1080/10426509408034261
State	Published - Jan 1 1994
Externally published	Yes

ASJC Scopus subject areas

Biochemistry
Organic Chemistry
Inorganic Chemistry

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10.1080/10426509408034261

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abstract = "The mechanism for the photocycloaddition of tetraarylthiiranes 1 with TCNE was probed by stereochemical and spectroscopic studies. Evidence is presented that the cation radical formed on irradiation of the charge transfer complexes of 1 and TCNE is a p-anisyl π-cation radical which then undergoes stereospecific ring opening by C-C bond cleavage.",

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AU - Jung, Woncheol

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N2 - The mechanism for the photocycloaddition of tetraarylthiiranes 1 with TCNE was probed by stereochemical and spectroscopic studies. Evidence is presented that the cation radical formed on irradiation of the charge transfer complexes of 1 and TCNE is a p-anisyl π-cation radical which then undergoes stereospecific ring opening by C-C bond cleavage.

AB - The mechanism for the photocycloaddition of tetraarylthiiranes 1 with TCNE was probed by stereochemical and spectroscopic studies. Evidence is presented that the cation radical formed on irradiation of the charge transfer complexes of 1 and TCNE is a p-anisyl π-cation radical which then undergoes stereospecific ring opening by C-C bond cleavage.

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UR - https://www.scopus.com/pages/publications/33749438161#tab=citedBy

U2 - 10.1080/10426509408034261

DO - 10.1080/10426509408034261

M3 - Article

AN - SCOPUS:33749438161

SN - 1042-6507

VL - 95

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EP - 424

JO - Phosphorus, Sulfur, and Silicon and the Related Elements

JF - Phosphorus, Sulfur, and Silicon and the Related Elements

IS - 1-4

ER -

Mechanism of the ring opening of a tetraaryl thiirane cation radical

Abstract

ASJC Scopus subject areas

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