MECHANISM OF ALKALI-CATALYZED CARBON/CO//2 REACTION.

Farhang Shadman; W. A. Punjak; D. A. Sams

MECHANISM OF ALKALI-CATALYZED CARBON/CO//2 REACTION.

Farhang Shadman, W. A. Punjak, D. A. Sams

Research output: Contribution to journal › Conference article › peer-review

Abstract

The mechanism of alkali-catalyzed C/CO//2 reaction is studied by a Temperature and Concentration Programmed Reaction (TCPR) technique. The proposed redox mechanism contains three surface complexes: minus CO//2M, minus COM and minus CM. The oxide groups are the intermediates during C/CO//2 gasification. The completely reduced form, minus CM, is the end product of catalyst reduction and is the precursor for catalyst loss. The stoichiometries of these surface groups are confirmed by oxygen and alkali balance.

Original language	English (US)
Journal	Annual Meeting - American Institute of Chemical Engineers
State	Published - 1985
Externally published	Yes

ASJC Scopus subject areas

General Engineering

Cite this

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title = "MECHANISM OF ALKALI-CATALYZED CARBON/CO//2 REACTION.",

abstract = "The mechanism of alkali-catalyzed C/CO//2 reaction is studied by a Temperature and Concentration Programmed Reaction (TCPR) technique. The proposed redox mechanism contains three surface complexes: minus CO//2M, minus COM and minus CM. The oxide groups are the intermediates during C/CO//2 gasification. The completely reduced form, minus CM, is the end product of catalyst reduction and is the precursor for catalyst loss. The stoichiometries of these surface groups are confirmed by oxygen and alkali balance.",

author = "Farhang Shadman and Punjak, {W. A.} and Sams, {D. A.}",

year = "1985",

language = "English (US)",

journal = "Annual Meeting - American Institute of Chemical Engineers",

issn = "0196-7282",

}

TY - JOUR

T1 - MECHANISM OF ALKALI-CATALYZED CARBON/CO//2 REACTION.

AU - Shadman, Farhang

AU - Punjak, W. A.

AU - Sams, D. A.

PY - 1985

Y1 - 1985

N2 - The mechanism of alkali-catalyzed C/CO//2 reaction is studied by a Temperature and Concentration Programmed Reaction (TCPR) technique. The proposed redox mechanism contains three surface complexes: minus CO//2M, minus COM and minus CM. The oxide groups are the intermediates during C/CO//2 gasification. The completely reduced form, minus CM, is the end product of catalyst reduction and is the precursor for catalyst loss. The stoichiometries of these surface groups are confirmed by oxygen and alkali balance.

AB - The mechanism of alkali-catalyzed C/CO//2 reaction is studied by a Temperature and Concentration Programmed Reaction (TCPR) technique. The proposed redox mechanism contains three surface complexes: minus CO//2M, minus COM and minus CM. The oxide groups are the intermediates during C/CO//2 gasification. The completely reduced form, minus CM, is the end product of catalyst reduction and is the precursor for catalyst loss. The stoichiometries of these surface groups are confirmed by oxygen and alkali balance.

UR - http://www.scopus.com/inward/record.url?scp=0022251990&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0022251990&partnerID=8YFLogxK

M3 - Conference article

AN - SCOPUS:0022251990

SN - 0196-7282

JO - Annual Meeting - American Institute of Chemical Engineers

JF - Annual Meeting - American Institute of Chemical Engineers

ER -

MECHANISM OF ALKALI-CATALYZED CARBON/CO//2 REACTION.

Abstract

ASJC Scopus subject areas

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