Measurement of the dipole moment of CF3CN

P. B. Foreman; K. R. Chien; J. R. Williams; S. G. Kukolich

doi:10.1016/0022-2852(74)90116-7

Measurement of the dipole moment of CF₃CN

P. B. Foreman
, K. R. Chien
, J. R. Williams
, S. G. Kukolich

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

The Stark effect was observed for K = 0 and K = 1, J = 1 → 2 transitions in CF₃CN. Measurements were made in a Stark modulated microwave spectrometer. The dipole moment obtained was μ = 1.262 ± 0.010 D. An analysis of the effects of electric field inhomogeneities on the observed Stark shifts for K = 0 and K = 1 states is included. Appropriate corrections are given for measuring linear Stark effects in a standard waveguide cell calibrated using a molecule with second-order Stark effect.

Original language	English (US)
Pages (from-to)	251-255
Number of pages	5
Journal	Journal of Molecular Spectroscopy
Volume	52
Issue number	2
DOIs	https://doi.org/10.1016/0022-2852(74)90116-7
State	Published - Aug 1974
Externally published	Yes

ASJC Scopus subject areas

Atomic and Molecular Physics, and Optics
Spectroscopy
Physical and Theoretical Chemistry

Access to Document

10.1016/0022-2852(74)90116-7

Cite this

@article{941d7fd1f3bc4443bb2aaad3b85955d1,

title = "Measurement of the dipole moment of CF3CN",

abstract = "The Stark effect was observed for K = 0 and K = 1, J = 1 → 2 transitions in CF3CN. Measurements were made in a Stark modulated microwave spectrometer. The dipole moment obtained was μ = 1.262 ± 0.010 D. An analysis of the effects of electric field inhomogeneities on the observed Stark shifts for K = 0 and K = 1 states is included. Appropriate corrections are given for measuring linear Stark effects in a standard waveguide cell calibrated using a molecule with second-order Stark effect.",

author = "Foreman, \{P. B.\} and Chien, \{K. R.\} and Williams, \{J. R.\} and Kukolich, \{S. G.\}",

year = "1974",

month = aug,

doi = "10.1016/0022-2852(74)90116-7",

language = "English (US)",

volume = "52",

pages = "251--255",

journal = "Journal of Molecular Spectroscopy",

issn = "0022-2852",

publisher = "Academic Press Inc.",

number = "2",

}

TY - JOUR

T1 - Measurement of the dipole moment of CF3CN

AU - Foreman, P. B.

AU - Chien, K. R.

AU - Williams, J. R.

AU - Kukolich, S. G.

PY - 1974/8

Y1 - 1974/8

N2 - The Stark effect was observed for K = 0 and K = 1, J = 1 → 2 transitions in CF3CN. Measurements were made in a Stark modulated microwave spectrometer. The dipole moment obtained was μ = 1.262 ± 0.010 D. An analysis of the effects of electric field inhomogeneities on the observed Stark shifts for K = 0 and K = 1 states is included. Appropriate corrections are given for measuring linear Stark effects in a standard waveguide cell calibrated using a molecule with second-order Stark effect.

AB - The Stark effect was observed for K = 0 and K = 1, J = 1 → 2 transitions in CF3CN. Measurements were made in a Stark modulated microwave spectrometer. The dipole moment obtained was μ = 1.262 ± 0.010 D. An analysis of the effects of electric field inhomogeneities on the observed Stark shifts for K = 0 and K = 1 states is included. Appropriate corrections are given for measuring linear Stark effects in a standard waveguide cell calibrated using a molecule with second-order Stark effect.

UR - https://www.scopus.com/pages/publications/0011201738

UR - https://www.scopus.com/pages/publications/0011201738#tab=citedBy

U2 - 10.1016/0022-2852(74)90116-7

DO - 10.1016/0022-2852(74)90116-7

M3 - Article

AN - SCOPUS:0011201738

SN - 0022-2852

VL - 52

SP - 251

EP - 255

JO - Journal of Molecular Spectroscopy

JF - Journal of Molecular Spectroscopy

IS - 2

ER -

Measurement of the dipole moment of CF₃CN

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this