Measurement of the dipole moment of CF3CN

P. B. Foreman; K. R. Chien; J. R. Williams; S. G. Kukolich

doi:10.1016/0022-2852(74)90116-7

Measurement of the dipole moment of CF₃CN

P. B. Foreman, K. R. Chien, J. R. Williams, S. G. Kukolich

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7 Scopus citations

Abstract

The Stark effect was observed for K = 0 and K = 1, J = 1 → 2 transitions in CF₃CN. Measurements were made in a Stark modulated microwave spectrometer. The dipole moment obtained was μ = 1.262 ± 0.010 D. An analysis of the effects of electric field inhomogeneities on the observed Stark shifts for K = 0 and K = 1 states is included. Appropriate corrections are given for measuring linear Stark effects in a standard waveguide cell calibrated using a molecule with second-order Stark effect.

Original language	English (US)
Pages (from-to)	251-255
Number of pages	5
Journal	Journal of Molecular Spectroscopy
Volume	52
Issue number	2
DOIs	https://doi.org/10.1016/0022-2852(74)90116-7
State	Published - Aug 1974
Externally published	Yes

ASJC Scopus subject areas

Atomic and Molecular Physics, and Optics
Spectroscopy
Physical and Theoretical Chemistry

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10.1016/0022-2852(74)90116-7

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abstract = "The Stark effect was observed for K = 0 and K = 1, J = 1 → 2 transitions in CF3CN. Measurements were made in a Stark modulated microwave spectrometer. The dipole moment obtained was μ = 1.262 ± 0.010 D. An analysis of the effects of electric field inhomogeneities on the observed Stark shifts for K = 0 and K = 1 states is included. Appropriate corrections are given for measuring linear Stark effects in a standard waveguide cell calibrated using a molecule with second-order Stark effect.",

author = "Foreman, {P. B.} and Chien, {K. R.} and Williams, {J. R.} and Kukolich, {S. G.}",

year = "1974",

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AU - Foreman, P. B.

AU - Chien, K. R.

AU - Williams, J. R.

AU - Kukolich, S. G.

PY - 1974/8

Y1 - 1974/8

N2 - The Stark effect was observed for K = 0 and K = 1, J = 1 → 2 transitions in CF3CN. Measurements were made in a Stark modulated microwave spectrometer. The dipole moment obtained was μ = 1.262 ± 0.010 D. An analysis of the effects of electric field inhomogeneities on the observed Stark shifts for K = 0 and K = 1 states is included. Appropriate corrections are given for measuring linear Stark effects in a standard waveguide cell calibrated using a molecule with second-order Stark effect.

AB - The Stark effect was observed for K = 0 and K = 1, J = 1 → 2 transitions in CF3CN. Measurements were made in a Stark modulated microwave spectrometer. The dipole moment obtained was μ = 1.262 ± 0.010 D. An analysis of the effects of electric field inhomogeneities on the observed Stark shifts for K = 0 and K = 1 states is included. Appropriate corrections are given for measuring linear Stark effects in a standard waveguide cell calibrated using a molecule with second-order Stark effect.

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EP - 255

JO - Journal of Molecular Spectroscopy

JF - Journal of Molecular Spectroscopy

IS - 2

ER -

Measurement of the dipole moment of CF₃CN

Abstract

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