Measurement of deuterium quadrupole coupling in CH3OD

K. H. Casleton; S. G. Kukolich

doi:10.1016/0009-2614(73)80105-8

Measurement of deuterium quadrupole coupling in CH₃OD

K. H. Casleton
, S. G. Kukolich

Research output: Contribution to journal › Article › peer-review

28 Scopus citations

Abstract

K = 1 → 0 transitions in CH₃OD for J = 1, 2, 3 and 4 E₂-type states were measured using a beam maser spectrometer with 6 kHz linewidth (fwhm). Analysis of J = 1 and J = 2 spectra provided a deuterium quadrupole coupling strength along the O-D bond dijection of eg_zzQ = 303 ± 12 kHz.

Original language	English (US)
Pages (from-to)	331-334
Number of pages	4
Journal	Chemical Physics Letters
Volume	22
Issue number	2
DOIs	https://doi.org/10.1016/0009-2614(73)80105-8
State	Published - Oct 1 1973
Externally published	Yes

ASJC Scopus subject areas

General Physics and Astronomy
Physical and Theoretical Chemistry

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10.1016/0009-2614(73)80105-8

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title = "Measurement of deuterium quadrupole coupling in CH3OD",

abstract = "K = 1 → 0 transitions in CH3OD for J = 1, 2, 3 and 4 E2-type states were measured using a beam maser spectrometer with 6 kHz linewidth (fwhm). Analysis of J = 1 and J = 2 spectra provided a deuterium quadrupole coupling strength along the O-D bond dijection of egzzQ = 303 ± 12 kHz.",

author = "Casleton, \{K. H.\} and Kukolich, \{S. G.\}",

note = "Funding Information: We wish to thank R.M. Lees for helpful correspondence on rotational properties of methanol. The support of the National Science Foundation is gratefully acknowledged (NSF Grant GP-21110, Structural Chemistry).",

year = "1973",

month = oct,

day = "1",

doi = "10.1016/0009-2614(73)80105-8",

language = "English (US)",

volume = "22",

pages = "331--334",

journal = "Chemical Physics Letters",

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publisher = "Elsevier B.V.",

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T1 - Measurement of deuterium quadrupole coupling in CH3OD

AU - Casleton, K. H.

AU - Kukolich, S. G.

N1 - Funding Information: We wish to thank R.M. Lees for helpful correspondence on rotational properties of methanol. The support of the National Science Foundation is gratefully acknowledged (NSF Grant GP-21110, Structural Chemistry).

PY - 1973/10/1

Y1 - 1973/10/1

N2 - K = 1 → 0 transitions in CH3OD for J = 1, 2, 3 and 4 E2-type states were measured using a beam maser spectrometer with 6 kHz linewidth (fwhm). Analysis of J = 1 and J = 2 spectra provided a deuterium quadrupole coupling strength along the O-D bond dijection of egzzQ = 303 ± 12 kHz.

AB - K = 1 → 0 transitions in CH3OD for J = 1, 2, 3 and 4 E2-type states were measured using a beam maser spectrometer with 6 kHz linewidth (fwhm). Analysis of J = 1 and J = 2 spectra provided a deuterium quadrupole coupling strength along the O-D bond dijection of egzzQ = 303 ± 12 kHz.

UR - https://www.scopus.com/pages/publications/0001742725

UR - https://www.scopus.com/pages/publications/0001742725#tab=citedBy

U2 - 10.1016/0009-2614(73)80105-8

DO - 10.1016/0009-2614(73)80105-8

M3 - Article

AN - SCOPUS:0001742725

SN - 0009-2614

VL - 22

SP - 331

EP - 334

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 2

ER -

Measurement of deuterium quadrupole coupling in CH₃OD

Abstract

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