Magnetic Suscepttbility Anisotropy, Molecular g Values, and Other Molecular Properties of Cyclopropane As Determined from Rotational Zeeman Studies of the Cyclopropane-H35 Cl and Cyclopropane-HC15N Complexes

P. D. Aldrich; S. G. Kukolich; E. J. Campbell; W. G. Read

doi:10.1021/ja00355a007

Magnetic Suscepttbility Anisotropy, Molecular g Values, and Other Molecular Properties of Cyclopropane As Determined from Rotational Zeeman Studies of the Cyclopropane-H³⁵ Cl and Cyclopropane-HC¹⁵N Complexes

P. D. Aldrich, S. G. Kukolich, E. J. Campbell, W. G. Read

Research output: Contribution to journal › Article › peer-review

22 Scopus citations

Abstract

A pulsed, Fourier-transform microwave spectrometer has been used to observe the rotational Zeeman effect with the cyclopropane-HCl and cyclopropane-HCN complexes. The molecular g values and magnetic susceptibility anisotropies have been determined for the cyclopropane-HCl complex and have been used to obtain the molecular quadrupole moment magnetic suscepttbility tensor elements as well as the paramagmetic and diamagnetic contributions, and the second momen of the electronic charge distribution. Certain Zeeman parameters along with zero-field rotational constants have been obtained for cyclopropane-HC¹⁵N. The Zeeman constants for both complexes have then been used to extract various magnetic properties of cyclopropane.

Original language	English (US)
Pages (from-to)	5569-5576
Number of pages	8
Journal	Journal of the American Chemical Society
Volume	105
Issue number	17
DOIs	https://doi.org/10.1021/ja00355a007
State	Published - Aug 1983
Externally published	Yes

ASJC Scopus subject areas

Catalysis
General Chemistry
Biochemistry
Colloid and Surface Chemistry

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Aldrich, P. D., Kukolich, S. G., Campbell, E. J., & Read, W. G. (1983). Magnetic Suscepttbility Anisotropy, Molecular g Values, and Other Molecular Properties of Cyclopropane As Determined from Rotational Zeeman Studies of the Cyclopropane-H³⁵ Cl and Cyclopropane-HC¹⁵N Complexes. Journal of the American Chemical Society, 105(17), 5569-5576. https://doi.org/10.1021/ja00355a007

Magnetic Suscepttbility Anisotropy, Molecular g Values, and Other Molecular Properties of Cyclopropane As Determined from Rotational Zeeman Studies of the Cyclopropane-H³⁵ Cl and Cyclopropane-HC¹⁵N Complexes. / Aldrich, P. D.; Kukolich, S. G.; Campbell, E. J. et al.
In: Journal of the American Chemical Society, Vol. 105, No. 17, 08.1983, p. 5569-5576.

Research output: Contribution to journal › Article › peer-review

Aldrich, PD, Kukolich, SG, Campbell, EJ & Read, WG 1983, 'Magnetic Suscepttbility Anisotropy, Molecular g Values, and Other Molecular Properties of Cyclopropane As Determined from Rotational Zeeman Studies of the Cyclopropane-H³⁵ Cl and Cyclopropane-HC¹⁵N Complexes', Journal of the American Chemical Society, vol. 105, no. 17, pp. 5569-5576. https://doi.org/10.1021/ja00355a007

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abstract = "A pulsed, Fourier-transform microwave spectrometer has been used to observe the rotational Zeeman effect with the cyclopropane-HCl and cyclopropane-HCN complexes. The molecular g values and magnetic susceptibility anisotropies have been determined for the cyclopropane-HCl complex and have been used to obtain the molecular quadrupole moment magnetic suscepttbility tensor elements as well as the paramagmetic and diamagnetic contributions, and the second momen of the electronic charge distribution. Certain Zeeman parameters along with zero-field rotational constants have been obtained for cyclopropane-HC15N. The Zeeman constants for both complexes have then been used to extract various magnetic properties of cyclopropane.",

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