Abstract
This chapter provides a review of the semiconducting properties of organic molecules that self-assemble into ordered liquid-crystalline mesophases, and discusses their performance in organic solar cells. The chapter is organized as follows: in the first section, the need for high-mobility materials in efficient solar cells is discussed; in the second section, various techniques used to determine the charge mobility in thin films are presented and compared; the third section reviews the basic properties of liquid-crystalline materials; then, the current 271 state-of-the-art developments in semiconducting liquid crystals are discussed. Finally, the properties of solar cells that are based on these self-ordering materials are presented.
Original language | English (US) |
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Title of host publication | Organic Photovoltaics |
Subtitle of host publication | Mechanisms, Materials, and Devices |
Publisher | CRC Press |
Pages | 271-298 |
Number of pages | 28 |
ISBN (Electronic) | 9781420026351 |
ISBN (Print) | 082475963X, 9780824759636 |
DOIs | |
State | Published - Jan 1 2017 |
Keywords
- Calamitic
- Child’s law
- Cholesteric
- Clearing temperature
- Columnar discotic
- Conductivity
- Cross-linking
- Discostic
- Disorder formalism
- Dispersive transport
- Energetic disorder
- Field-effect transistor
- Grain boundaries
- Liquid crystal
- Lyotropic
- Mesophase
- Mobility
- Mobility pre-factor
- Nematic
- Nematic discotic
- Order parameter
- Phase
- Phase transition
- Positional disorder
- Pulsed radiolysis time-resolved microwave
- Smectic
- Space-charge limited current
- Thermotropic
- Time-of-flight
- Transition temperature
ASJC Scopus subject areas
- General Engineering
- General Environmental Science