Isoindigo-3,4-Difluorothiophene Polymer Acceptors Yield “All-Polymer” Bulk-Heterojunction Solar Cells with over 7 % Efficiency

Shengjian Liu; Yuliar Firdaus; Simil Thomas; Zhipeng Kan; Federico Cruciani; Sergei Lopatin; Jean Luc Bredas; Pierre M. Beaujuge

doi:10.1002/anie.201709509

Isoindigo-3,4-Difluorothiophene Polymer Acceptors Yield “All-Polymer” Bulk-Heterojunction Solar Cells with over 7 % Efficiency

Shengjian Liu
, Yuliar Firdaus
, Simil Thomas
, Zhipeng Kan
, Federico Cruciani
, Sergei Lopatin
, Jean Luc Bredas
, Pierre M. Beaujuge

Research output: Contribution to journal › Article › peer-review

71 Scopus citations

Abstract

Poly(isoindigo-alt-3,4-difluorothiophene) (PIID[2F]T) analogues used as “polymer acceptors” in bulk-heterojunction (BHJ) solar cells achieve >7 % efficiency when used in conjunction with the polymer donor PBFTAZ (model system; copolymer of benzo[1,2-b:4,5-b′]dithiophene and 5,6-difluorobenzotriazole). Considering that most efficient polymer-acceptor alternatives to fullerenes (e.g. PC₆₁BM or its C₇₁ derivative) are based on perylenediimide or naphthalenediimide motifs thus far, branched alkyl-substituted PIID[2F]T polymers are particularly promising non-fullerene candidates for “all-polymer” BHJ solar cells.

Original language	English (US)
Pages (from-to)	531-535
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	57
Issue number	2
DOIs	https://doi.org/10.1002/anie.201709509
State	Published - Jan 8 2018
Externally published	Yes

Keywords

3,4-difluorothiophene
all-polymer solar cells
isoindigo
polymer acceptors
solar cells

ASJC Scopus subject areas

Catalysis
General Chemistry

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10.1002/anie.201709509

Cite this

@article{f9315cb73ba2488192dc2969660bd69b,

title = "Isoindigo-3,4-Difluorothiophene Polymer Acceptors Yield “All-Polymer” Bulk-Heterojunction Solar Cells with over 7 \% Efficiency",

abstract = "Poly(isoindigo-alt-3,4-difluorothiophene) (PIID[2F]T) analogues used as “polymer acceptors” in bulk-heterojunction (BHJ) solar cells achieve >7 \% efficiency when used in conjunction with the polymer donor PBFTAZ (model system; copolymer of benzo[1,2-b:4,5-b′]dithiophene and 5,6-difluorobenzotriazole). Considering that most efficient polymer-acceptor alternatives to fullerenes (e.g. PC61BM or its C71 derivative) are based on perylenediimide or naphthalenediimide motifs thus far, branched alkyl-substituted PIID[2F]T polymers are particularly promising non-fullerene candidates for “all-polymer” BHJ solar cells.",

keywords = "3,4-difluorothiophene, all-polymer solar cells, isoindigo, polymer acceptors, solar cells",

author = "Shengjian Liu and Yuliar Firdaus and Simil Thomas and Zhipeng Kan and Federico Cruciani and Sergei Lopatin and Bredas, \{Jean Luc\} and Beaujuge, \{Pierre M.\}",

note = "Publisher Copyright: {\textcopyright} 2018 Wiley-VCH Verlag GmbH \& Co. KGaA, Weinheim",

year = "2018",

month = jan,

day = "8",

doi = "10.1002/anie.201709509",

language = "English (US)",

volume = "57",

pages = "531--535",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley and Sons Ltd",

number = "2",

}

TY - JOUR

T1 - Isoindigo-3,4-Difluorothiophene Polymer Acceptors Yield “All-Polymer” Bulk-Heterojunction Solar Cells with over 7 % Efficiency

AU - Liu, Shengjian

AU - Firdaus, Yuliar

AU - Thomas, Simil

AU - Kan, Zhipeng

AU - Cruciani, Federico

AU - Lopatin, Sergei

AU - Bredas, Jean Luc

AU - Beaujuge, Pierre M.

PY - 2018/1/8

Y1 - 2018/1/8

N2 - Poly(isoindigo-alt-3,4-difluorothiophene) (PIID[2F]T) analogues used as “polymer acceptors” in bulk-heterojunction (BHJ) solar cells achieve >7 % efficiency when used in conjunction with the polymer donor PBFTAZ (model system; copolymer of benzo[1,2-b:4,5-b′]dithiophene and 5,6-difluorobenzotriazole). Considering that most efficient polymer-acceptor alternatives to fullerenes (e.g. PC61BM or its C71 derivative) are based on perylenediimide or naphthalenediimide motifs thus far, branched alkyl-substituted PIID[2F]T polymers are particularly promising non-fullerene candidates for “all-polymer” BHJ solar cells.

AB - Poly(isoindigo-alt-3,4-difluorothiophene) (PIID[2F]T) analogues used as “polymer acceptors” in bulk-heterojunction (BHJ) solar cells achieve >7 % efficiency when used in conjunction with the polymer donor PBFTAZ (model system; copolymer of benzo[1,2-b:4,5-b′]dithiophene and 5,6-difluorobenzotriazole). Considering that most efficient polymer-acceptor alternatives to fullerenes (e.g. PC61BM or its C71 derivative) are based on perylenediimide or naphthalenediimide motifs thus far, branched alkyl-substituted PIID[2F]T polymers are particularly promising non-fullerene candidates for “all-polymer” BHJ solar cells.

KW - 3,4-difluorothiophene

KW - all-polymer solar cells

KW - isoindigo

KW - polymer acceptors

KW - solar cells

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UR - https://www.scopus.com/pages/publications/85042104997#tab=citedBy

U2 - 10.1002/anie.201709509

DO - 10.1002/anie.201709509

M3 - Article

C2 - 29154413

AN - SCOPUS:85042104997

SN - 1433-7851

VL - 57

SP - 531

EP - 535

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 2

ER -

Isoindigo-3,4-Difluorothiophene Polymer Acceptors Yield “All-Polymer” Bulk-Heterojunction Solar Cells with over 7 % Efficiency

Abstract

Keywords

ASJC Scopus subject areas

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