Inverse vulcanization of elemental sulfur with 1,4-diphenylbutadiyne for cathode materials in Li-S batteries

Philip T. Dirlam; Adam G. Simmonds; Tristan S. Kleine; Ngoc A. Nguyen; Laura E. Anderson; Adam O. Klever; Alexander Florian; Philip J. Costanzo; Patrick Theato; Michael E. Mackay; Richard S. Glass; Kookheon Char; Jeffrey Pyun

doi:10.1039/c5ra01188d

Inverse vulcanization of elemental sulfur with 1,4-diphenylbutadiyne for cathode materials in Li-S batteries

Philip T. Dirlam
, Adam G. Simmonds
, Tristan S. Kleine
, Ngoc A. Nguyen
, Laura E. Anderson
, Adam O. Klever
, Alexander Florian
, Philip J. Costanzo
, Patrick Theato
, Michael E. Mackay
, Richard S. Glass
, Kookheon Char
, Jeffrey Pyun

Chemistry and Biochemistry

Research output: Contribution to journal › Article › peer-review

168 Scopus citations

Abstract

High sulfur content copolymers were prepared via inverse vulcanization of sulfur with 1,4-diphenylbutadiyne (DiPhDY) for use as the active cathode material in lithium-sulfur batteries. These sulfur-rich polymers exhibited excellent capacity retention (800 mA h g^-1 at 300 cycles) and extended battery lifetimes of over 850 cycles at C/5 rate.

Original language	English (US)
Pages (from-to)	24718-24722
Number of pages	5
Journal	RSC Advances
Volume	5
Issue number	31
DOIs	https://doi.org/10.1039/c5ra01188d
State	Published - 2015

ASJC Scopus subject areas

General Chemistry
General Chemical Engineering

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10.1039/c5ra01188d

Cite this

Dirlam, P. T., Simmonds, A. G., Kleine, T. S., Nguyen, N. A., Anderson, L. E., Klever, A. O., Florian, A., Costanzo, P. J., Theato, P., Mackay, M. E., Glass, R. S., Char, K., & Pyun, J. (2015). Inverse vulcanization of elemental sulfur with 1,4-diphenylbutadiyne for cathode materials in Li-S batteries. RSC Advances, 5(31), 24718-24722. https://doi.org/10.1039/c5ra01188d

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title = "Inverse vulcanization of elemental sulfur with 1,4-diphenylbutadiyne for cathode materials in Li-S batteries",

abstract = "High sulfur content copolymers were prepared via inverse vulcanization of sulfur with 1,4-diphenylbutadiyne (DiPhDY) for use as the active cathode material in lithium-sulfur batteries. These sulfur-rich polymers exhibited excellent capacity retention (800 mA h g-1 at 300 cycles) and extended battery lifetimes of over 850 cycles at C/5 rate.",

author = "Dirlam, \{Philip T.\} and Simmonds, \{Adam G.\} and Kleine, \{Tristan S.\} and Nguyen, \{Ngoc A.\} and Anderson, \{Laura E.\} and Klever, \{Adam O.\} and Alexander Florian and Costanzo, \{Philip J.\} and Patrick Theato and Mackay, \{Michael E.\} and Glass, \{Richard S.\} and Kookheon Char and Jeffrey Pyun",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2015.",

year = "2015",

doi = "10.1039/c5ra01188d",

language = "English (US)",

volume = "5",

pages = "24718--24722",

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AU - Dirlam, Philip T.

AU - Simmonds, Adam G.

AU - Kleine, Tristan S.

AU - Nguyen, Ngoc A.

AU - Anderson, Laura E.

AU - Klever, Adam O.

AU - Florian, Alexander

AU - Costanzo, Philip J.

AU - Theato, Patrick

AU - Mackay, Michael E.

AU - Glass, Richard S.

AU - Char, Kookheon

AU - Pyun, Jeffrey

PY - 2015

Y1 - 2015

N2 - High sulfur content copolymers were prepared via inverse vulcanization of sulfur with 1,4-diphenylbutadiyne (DiPhDY) for use as the active cathode material in lithium-sulfur batteries. These sulfur-rich polymers exhibited excellent capacity retention (800 mA h g-1 at 300 cycles) and extended battery lifetimes of over 850 cycles at C/5 rate.

AB - High sulfur content copolymers were prepared via inverse vulcanization of sulfur with 1,4-diphenylbutadiyne (DiPhDY) for use as the active cathode material in lithium-sulfur batteries. These sulfur-rich polymers exhibited excellent capacity retention (800 mA h g-1 at 300 cycles) and extended battery lifetimes of over 850 cycles at C/5 rate.

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UR - https://www.scopus.com/pages/publications/84924728065#tab=citedBy

U2 - 10.1039/c5ra01188d

DO - 10.1039/c5ra01188d

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JO - RSC Advances

JF - RSC Advances

IS - 31

ER -

Inverse vulcanization of elemental sulfur with 1,4-diphenylbutadiyne for cathode materials in Li-S batteries

Abstract

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