Influence of Transboundary Pollution on the Variability of Surface Ozone Concentrations in the Desert Southwest of the U.S. Case Study for Arizona

Arizona, a rapidly growing state in the southwestern U.S., faces ozone pollution challenges, including nonattainment areas in Yuma and Maricopa counties influenced by neighboring state pollution transport. In this study, we use five-year (2017–2021) hourly back-trajectories and O₃ concentration data for concentration-weighted trajectory (CWT) analysis to identify transport pathways and potential source regions of O₃ at six monitoring sites in Arizona. We divide the data into five seasons (winter, spring, dry summer, monsoon summer, and fall) to examine variations in O₃ concentration and transport across sites and seasons. The highest mean O₃ concentrations occur during spring (37–49 ppb), dry summer (39–51 ppb), and monsoon summer (34–49 ppb), while winter (19–41 ppb) exhibits the lowest seasonal mean. The CWT results reveal that high O₃ concentrations (≥40 ppb) in Arizona, with the exception of Phoenix and Tucson sites, are influenced significantly by regional and international transport, especially in spring (14.9–35.4%) and dry summer (12.7–26.9%). The major potential source areas (excluding the Phoenix and Tucson sites) are predominantly located outside Arizona. This study highlights the critical role of pollution transport in influencing O₃ variability within Arizona and will be valuable in shaping pollution control strategies in the future.