Influence of inter- and intra-valley carrier dynamics on the optical properties of monolayer TMDCs

J. Hader, Jerome V Moloney, J. Neuhaus, S. W. Koch

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

First principle DFT-based microscopic many-body models are used to investigate inter- and intra-valley carrier dynamics in the monolayer transition-metal dichalcogenide MoTe2. Electron-electron and electron-phonon scatterings are calculated for transitions within the full Brillouin zone to determine overall carrier relaxation timescales as well as intra- and inter-valley transition rates. For excitation above the barriers separating bandstructure valleys carriers are found to relax on a ten femtosecond timescale into hot quasi-Fermi distributions at the band minima. Subsequently, the hot carrier plasma is cooled down on a picosecond timescale predominantly through emission of optical phonons. Local carrier occupations lead to strong energy renormalizations in momentum space. However, for the material investigated here, the global energy minimum remains at the K-points once carriers relax into global quasi-Fermi distributions. No transition from a direct to an indirect bandgap is observed.

Original languageEnglish (US)
Title of host publication2D Photonic Materials and Devices V
EditorsArka Majumdar, Carlos M. Torres, Hui Deng
PublisherSPIE
ISBN (Electronic)9781510648777
DOIs
StatePublished - 2022
Event2D Photonic Materials and Devices V 2022 - Virtual, Online
Duration: Feb 20 2022Feb 24 2022

Publication series

NameProceedings of SPIE - The International Society for Optical Engineering
Volume12003
ISSN (Print)0277-786X
ISSN (Electronic)1996-756X

Conference

Conference2D Photonic Materials and Devices V 2022
CityVirtual, Online
Period2/20/222/24/22

Keywords

  • carrier scattering
  • density functional theory
  • Dirac Bloch equations
  • many-body theory
  • TMDC

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics
  • Computer Science Applications
  • Applied Mathematics
  • Electrical and Electronic Engineering

Fingerprint

Dive into the research topics of 'Influence of inter- and intra-valley carrier dynamics on the optical properties of monolayer TMDCs'. Together they form a unique fingerprint.

Cite this