TY - JOUR
T1 - Identification and characterization of 1,2-BN cyclohexene using microwave spectroscopy
AU - Kukolich, Stephen G.
AU - Sun, Ming
AU - Daly, Adam M.
AU - Luo, Wei
AU - Zakharov, Lev N.
AU - Liu, Shih Yuan
N1 - Publisher Copyright:
© 2015 Elsevier B.V. All rights reserved.
PY - 2015/10/16
Y1 - 2015/10/16
N2 - 1,2-BN cyclohexene has been produced from 1,2-BN cyclohexane through the loss of H2 and characterized and identified using a pulsed-beam Fourier-transform microwave spectrometer. Microwave spectra were measured in the frequency range of 5.5-12.5 GHz, providing accurate rotational constants and quadrupole coupling strengths. Results of high level calculations allowed clear assignment of the spectra to 1,2-BN cyclohexene. Heating the initial compound, 1,2-BN cyclohexane, to 60 °C in a 1 atm neon stream results in the loss of H2 and conversion to 1,2-BN cyclohexene and this appears to be the first characterization of this compound as the 1,2-BN cyclohexene monomer.
AB - 1,2-BN cyclohexene has been produced from 1,2-BN cyclohexane through the loss of H2 and characterized and identified using a pulsed-beam Fourier-transform microwave spectrometer. Microwave spectra were measured in the frequency range of 5.5-12.5 GHz, providing accurate rotational constants and quadrupole coupling strengths. Results of high level calculations allowed clear assignment of the spectra to 1,2-BN cyclohexene. Heating the initial compound, 1,2-BN cyclohexane, to 60 °C in a 1 atm neon stream results in the loss of H2 and conversion to 1,2-BN cyclohexene and this appears to be the first characterization of this compound as the 1,2-BN cyclohexene monomer.
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U2 - 10.1016/j.cplett.2015.09.009
DO - 10.1016/j.cplett.2015.09.009
M3 - Article
AN - SCOPUS:84941765480
SN - 0009-2614
VL - 639
SP - 88
EP - 92
JO - Chemical Physics Letters
JF - Chemical Physics Letters
ER -