TY - JOUR
T1 - Hole- and Electron-Vibrational Couplings in Oligoacene Crystals
T2 - Intramolecular Contributions
AU - Coropceanu, V.
AU - Malagoli, M.
AU - da Silva Filho, D. A.
AU - Gruhn, N. E.
AU - Bill, T. G.
AU - Brédas, J. L.
PY - 2002
Y1 - 2002
N2 - The hole-vibrational coupling is reported for anthracene, tetracene, and pentacene on the basis of a joint experimental and theoretical study of ionization spectra using high-resolution gas-phase photoelectron spectroscopy and first-principles correlated quantum-mechanical calculations. The hole-vibrational coupling is found to be significantly smaller than the electron-vibrational coupling in the case of these oligomers; however, both quantities are predicted to converge to the same value when increasing the chain length.
AB - The hole-vibrational coupling is reported for anthracene, tetracene, and pentacene on the basis of a joint experimental and theoretical study of ionization spectra using high-resolution gas-phase photoelectron spectroscopy and first-principles correlated quantum-mechanical calculations. The hole-vibrational coupling is found to be significantly smaller than the electron-vibrational coupling in the case of these oligomers; however, both quantities are predicted to converge to the same value when increasing the chain length.
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U2 - 10.1103/PhysRevLett.89.275503
DO - 10.1103/PhysRevLett.89.275503
M3 - Article
AN - SCOPUS:4043076618
SN - 0031-9007
VL - 89
JO - Physical review letters
JF - Physical review letters
IS - 27
ER -