Highly sulfonated polyelectrolytes through friedel-crafts sulfonylation of polyarylenes

Stephen M. Budy; Douglas A. Loy

doi:10.1002/pola.27139

Highly sulfonated polyelectrolytes through friedel-crafts sulfonylation of polyarylenes

Stephen M. Budy, Douglas A. Loy

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

Friedel-Craft sulfonylation of polyarylenes with 1,3,5- benzenetrisulfonylchloride has been demonstrated to yield soluble and processable, highly sulfonated polyarylenes (IEC 1.9-2.9 milliequivalents/gram) that do not swell in water and are stable to 280 °C. The new method provides an alternative, more efficient approach to sulfonating aromatic polymers.

Original language	English (US)
Pages (from-to)	1381-1384
Number of pages	4
Journal	Journal of Polymer Science, Part A: Polymer Chemistry
Volume	52
Issue number	10
DOIs	https://doi.org/10.1002/pola.27139
State	Published - May 15 2014

Keywords

Friedel-Crafts sulfonylation
Polyelectrolyte
modification
phenylated polyphenylene
polyaromatics
polyarylene
polymer electrolyte
polymer modification sulfonated polyelectrolytes
sulfone linkages

ASJC Scopus subject areas

Polymers and Plastics
Organic Chemistry
Materials Chemistry

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10.1002/pola.27139

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title = "Highly sulfonated polyelectrolytes through friedel-crafts sulfonylation of polyarylenes",

abstract = "Friedel-Craft sulfonylation of polyarylenes with 1,3,5- benzenetrisulfonylchloride has been demonstrated to yield soluble and processable, highly sulfonated polyarylenes (IEC 1.9-2.9 milliequivalents/gram) that do not swell in water and are stable to 280 °C. The new method provides an alternative, more efficient approach to sulfonating aromatic polymers.",

keywords = "Friedel-Crafts sulfonylation, Polyelectrolyte, modification, phenylated polyphenylene, polyaromatics, polyarylene, polymer electrolyte, polymer modification sulfonated polyelectrolytes, sulfone linkages",

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year = "2014",

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doi = "10.1002/pola.27139",

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journal = "Journal of Polymer Science, Part A: Polymer Chemistry",

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T1 - Highly sulfonated polyelectrolytes through friedel-crafts sulfonylation of polyarylenes

AU - Budy, Stephen M.

AU - Loy, Douglas A.

PY - 2014/5/15

Y1 - 2014/5/15

N2 - Friedel-Craft sulfonylation of polyarylenes with 1,3,5- benzenetrisulfonylchloride has been demonstrated to yield soluble and processable, highly sulfonated polyarylenes (IEC 1.9-2.9 milliequivalents/gram) that do not swell in water and are stable to 280 °C. The new method provides an alternative, more efficient approach to sulfonating aromatic polymers.

AB - Friedel-Craft sulfonylation of polyarylenes with 1,3,5- benzenetrisulfonylchloride has been demonstrated to yield soluble and processable, highly sulfonated polyarylenes (IEC 1.9-2.9 milliequivalents/gram) that do not swell in water and are stable to 280 °C. The new method provides an alternative, more efficient approach to sulfonating aromatic polymers.

KW - Friedel-Crafts sulfonylation

KW - Polyelectrolyte

KW - modification

KW - phenylated polyphenylene

KW - polyaromatics

KW - polyarylene

KW - polymer electrolyte

KW - polymer modification sulfonated polyelectrolytes

KW - sulfone linkages

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M3 - Article

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JO - Journal of Polymer Science, Part A: Polymer Chemistry

JF - Journal of Polymer Science, Part A: Polymer Chemistry

IS - 10

ER -

Highly sulfonated polyelectrolytes through friedel-crafts sulfonylation of polyarylenes

Abstract

Keywords

ASJC Scopus subject areas

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