Heavy atom effect on nonlinear absorption and optical limiting characteristics of 5,10,15,20-(tetratolyl) porphyrinato phosphorus (V) dichloride

P. Prem Kiran; N. K.M. Naga Srinivas; D. Raghunath Reddy; Bhaskar G. Maiya; Aditya Dharmadhikari; Arvinder S. Sandhu; G. Ravindra Kumar; D. Narayana Rao

doi:10.1016/S0030-4018(02)01112-4

Heavy atom effect on nonlinear absorption and optical limiting characteristics of 5,10,15,20-(tetratolyl) porphyrinato phosphorus (V) dichloride

P. Prem Kiran, N. K.M. Naga Srinivas, D. Raghunath Reddy, Bhaskar G. Maiya, Aditya Dharmadhikari, Arvinder S. Sandhu, G. Ravindra Kumar, D. Narayana Rao

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38 Scopus citations

Abstract

Optical limiting performance and third-order nonlinearity χ⁽³⁾ are investigated in 5,10,15,20-(tetratolyl) porphyrinato phosphorus (V) dichloride ([(TTP)P^VCl₂]⁺). Heavy atom effect exerted by the two axial chlorides is found to result in low fluorescence yield (∅_fl), shorter lifetimes of S₁, T₁ and faster intersystem crossing (ISC), leading to larger excited state absorption (ESA) from T₁ → T_n. This phenomenon is found to lower the limiting threshold by 30 times and increase the second hyperpolarizability by one and three orders in ps and ns time regimes, respectively.

Original language	English (US)
Pages (from-to)	347-352
Number of pages	6
Journal	Optics Communications
Volume	202
Issue number	4-6
DOIs	https://doi.org/10.1016/S0030-4018(02)01112-4
State	Published - Feb 15 2002

Keywords

Exicited state absorption
Heavy atom effect
Optical limiting
Porphyrin

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Atomic and Molecular Physics, and Optics
Physical and Theoretical Chemistry
Electrical and Electronic Engineering

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10.1016/S0030-4018(02)01112-4

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Prem Kiran, P., Naga Srinivas, N. K. M., Raghunath Reddy, D., Maiya, B. G., Dharmadhikari, A., Sandhu, A. S., Ravindra Kumar, G., & Narayana Rao, D. (2002). Heavy atom effect on nonlinear absorption and optical limiting characteristics of 5,10,15,20-(tetratolyl) porphyrinato phosphorus (V) dichloride. Optics Communications, 202(4-6), 347-352. https://doi.org/10.1016/S0030-4018(02)01112-4

Prem Kiran, P, Naga Srinivas, NKM, Raghunath Reddy, D, Maiya, BG, Dharmadhikari, A, Sandhu, AS, Ravindra Kumar, G & Narayana Rao, D 2002, 'Heavy atom effect on nonlinear absorption and optical limiting characteristics of 5,10,15,20-(tetratolyl) porphyrinato phosphorus (V) dichloride', Optics Communications, vol. 202, no. 4-6, pp. 347-352. https://doi.org/10.1016/S0030-4018(02)01112-4

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title = "Heavy atom effect on nonlinear absorption and optical limiting characteristics of 5,10,15,20-(tetratolyl) porphyrinato phosphorus (V) dichloride",

abstract = "Optical limiting performance and third-order nonlinearity χ(3) are investigated in 5,10,15,20-(tetratolyl) porphyrinato phosphorus (V) dichloride ([(TTP)PVCl2]+). Heavy atom effect exerted by the two axial chlorides is found to result in low fluorescence yield (∅fl), shorter lifetimes of S1, T1 and faster intersystem crossing (ISC), leading to larger excited state absorption (ESA) from T1 → Tn. This phenomenon is found to lower the limiting threshold by 30 times and increase the second hyperpolarizability by one and three orders in ps and ns time regimes, respectively.",

keywords = "Exicited state absorption, Heavy atom effect, Optical limiting, Porphyrin",

author = "{Prem Kiran}, P. and {Naga Srinivas}, {N. K.M.} and {Raghunath Reddy}, D. and Maiya, {Bhaskar G.} and Aditya Dharmadhikari and Sandhu, {Arvinder S.} and {Ravindra Kumar}, G. and {Narayana Rao}, D.",

note = "Funding Information: Financial support from BRNS, DRDO and CSIR is acknowledged.",

year = "2002",

month = feb,

day = "15",

doi = "10.1016/S0030-4018(02)01112-4",

language = "English (US)",

volume = "202",

pages = "347--352",

journal = "Optics Communications",

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number = "4-6",

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T1 - Heavy atom effect on nonlinear absorption and optical limiting characteristics of 5,10,15,20-(tetratolyl) porphyrinato phosphorus (V) dichloride

AU - Prem Kiran, P.

AU - Naga Srinivas, N. K.M.

AU - Raghunath Reddy, D.

AU - Maiya, Bhaskar G.

AU - Dharmadhikari, Aditya

AU - Sandhu, Arvinder S.

AU - Ravindra Kumar, G.

AU - Narayana Rao, D.

N1 - Funding Information: Financial support from BRNS, DRDO and CSIR is acknowledged.

PY - 2002/2/15

Y1 - 2002/2/15

N2 - Optical limiting performance and third-order nonlinearity χ(3) are investigated in 5,10,15,20-(tetratolyl) porphyrinato phosphorus (V) dichloride ([(TTP)PVCl2]+). Heavy atom effect exerted by the two axial chlorides is found to result in low fluorescence yield (∅fl), shorter lifetimes of S1, T1 and faster intersystem crossing (ISC), leading to larger excited state absorption (ESA) from T1 → Tn. This phenomenon is found to lower the limiting threshold by 30 times and increase the second hyperpolarizability by one and three orders in ps and ns time regimes, respectively.

AB - Optical limiting performance and third-order nonlinearity χ(3) are investigated in 5,10,15,20-(tetratolyl) porphyrinato phosphorus (V) dichloride ([(TTP)PVCl2]+). Heavy atom effect exerted by the two axial chlorides is found to result in low fluorescence yield (∅fl), shorter lifetimes of S1, T1 and faster intersystem crossing (ISC), leading to larger excited state absorption (ESA) from T1 → Tn. This phenomenon is found to lower the limiting threshold by 30 times and increase the second hyperpolarizability by one and three orders in ps and ns time regimes, respectively.

KW - Exicited state absorption

KW - Heavy atom effect

KW - Optical limiting

KW - Porphyrin

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U2 - 10.1016/S0030-4018(02)01112-4

DO - 10.1016/S0030-4018(02)01112-4

M3 - Article

AN - SCOPUS:0037083381

SN - 0030-4018

VL - 202

SP - 347

EP - 352

JO - Optics Communications

JF - Optics Communications

IS - 4-6

ER -

Heavy atom effect on nonlinear absorption and optical limiting characteristics of 5,10,15,20-(tetratolyl) porphyrinato phosphorus (V) dichloride

Abstract

Keywords

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