TY - JOUR
T1 - Glassformer fragilities and landscape excitation profiles by simple calorimetric and theoretical methods
AU - Angell, C. A.
AU - Green, J. L.
AU - Ito, K.
AU - Lucas, P.
AU - Richards, B. E.
N1 - Funding Information:
This work has been carried out under the auspices of the NSF under Solid State Chemistry grant no. DMR 9614531. The authors have benefited from helpful discussions with Burkhardt Geil and Robin Speedy, and particularly Paul Madden who drew our attention to [41].
PY - 1999
Y1 - 1999
N2 - In this paper we introduce two key notions related to understanding the 'glassy state' problem. One is the notion of the 'excitation profile' for an amorphous system and the other is the notion of the 'simple glassformer'. The attributes of the latter may be used, in quite different ways, to calculate and characterize the former. The excitation profile itself directly reflects the combined phonon/configuron density of states, which in turn determines the liquid fragility. In effect, we are examining the equivalent, for liquids, of the low temperature Einstein-Debye regime for solids though, in the liquid heat capacity case, there is no equivalent of the Dulong/Pettit classical limit for solids. To quantify these notions we apply simple calorimetric methods in a novel manner. First we use DTA techniques to define some glass-forming systems that are molecularly simpler than any described before, including cases which are 80 mol% CS2, or 100% S2Cl2. We then use the same data to obtain the fragility of these simple systems by a new approach, the 'reduced glass transition width' method. This method will be justified using data on a wider variety of well characterized glassformers, for which the unambiguous F 1/2 fragility measures are available. We also describe a new DTA method for obtaining F 1/2 fragilities in a single scan. We draw surprising conclusions about the fragility of the simplest molecular glassformers, the mixed LJ glasses, which have been much studied by molecular dynamics computer simulation. These ideas are then applied to a different kind of simple glass - one whose thermodynamics is dominated by breaking and making of covalent bonds - for which case the excitation profile can be straight-forwardly modeled. Comparisons with the profile obtained from computer studies of the molecularly simple glasses are made, and the differences in profiles implied for strong vs. fragile systems are discussed. The origin of fragility in the relation between the vibrational and configurational densities of states is discussed, and the conditions under which high fragility can convert to a first order liquid-liquid transition, is outlined.
AB - In this paper we introduce two key notions related to understanding the 'glassy state' problem. One is the notion of the 'excitation profile' for an amorphous system and the other is the notion of the 'simple glassformer'. The attributes of the latter may be used, in quite different ways, to calculate and characterize the former. The excitation profile itself directly reflects the combined phonon/configuron density of states, which in turn determines the liquid fragility. In effect, we are examining the equivalent, for liquids, of the low temperature Einstein-Debye regime for solids though, in the liquid heat capacity case, there is no equivalent of the Dulong/Pettit classical limit for solids. To quantify these notions we apply simple calorimetric methods in a novel manner. First we use DTA techniques to define some glass-forming systems that are molecularly simpler than any described before, including cases which are 80 mol% CS2, or 100% S2Cl2. We then use the same data to obtain the fragility of these simple systems by a new approach, the 'reduced glass transition width' method. This method will be justified using data on a wider variety of well characterized glassformers, for which the unambiguous F 1/2 fragility measures are available. We also describe a new DTA method for obtaining F 1/2 fragilities in a single scan. We draw surprising conclusions about the fragility of the simplest molecular glassformers, the mixed LJ glasses, which have been much studied by molecular dynamics computer simulation. These ideas are then applied to a different kind of simple glass - one whose thermodynamics is dominated by breaking and making of covalent bonds - for which case the excitation profile can be straight-forwardly modeled. Comparisons with the profile obtained from computer studies of the molecularly simple glasses are made, and the differences in profiles implied for strong vs. fragile systems are discussed. The origin of fragility in the relation between the vibrational and configurational densities of states is discussed, and the conditions under which high fragility can convert to a first order liquid-liquid transition, is outlined.
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M3 - Conference article
AN - SCOPUS:0033309440
SN - 1388-6150
VL - 57
SP - 717
EP - 736
JO - Journal of Thermal Analysis and Calorimetry
JF - Journal of Thermal Analysis and Calorimetry
IS - 3
T2 - Proceedings of the 1998 International Symposium on New Frontier of Thermal Studies of Materials
Y2 - 26 October 1998 through 27 October 1998
ER -