Further studies of 3d transition metal cyanides: The pure rotational spectrum of NiCN (X2Δi)

P. M. Sheridan; L. M. Ziurys

doi:10.1063/1.1557471

Further studies of 3d transition metal cyanides: The pure rotational spectrum of NiCN (X²Δ_i)

P. M. Sheridan, L. M. Ziurys

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Abstract

Measurement of the pure rotational spectrum of NiCN in its ²Δ_i ground electronic state has enabled the identification of both spin-orbit components of this molecule, as well as new vibronic levels. It has confirmed the linear cyanide structure of this radical, as indicated by optical studies. In the higher lying spin-orbit sublevel, significant lambda-doubling interactions are observed, as is found in NiH(X²Δ_i).

Original language	English (US)
Pages (from-to)	6370-6379
Number of pages	10
Journal	Journal of Chemical Physics
Volume	118
Issue number	14
DOIs	https://doi.org/10.1063/1.1557471
State	Published - Apr 8 2003

ASJC Scopus subject areas

General Physics and Astronomy
Physical and Theoretical Chemistry

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abstract = "Measurement of the pure rotational spectrum of NiCN in its 2Δi ground electronic state has enabled the identification of both spin-orbit components of this molecule, as well as new vibronic levels. It has confirmed the linear cyanide structure of this radical, as indicated by optical studies. In the higher lying spin-orbit sublevel, significant lambda-doubling interactions are observed, as is found in NiH(X2Δi).",

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N2 - Measurement of the pure rotational spectrum of NiCN in its 2Δi ground electronic state has enabled the identification of both spin-orbit components of this molecule, as well as new vibronic levels. It has confirmed the linear cyanide structure of this radical, as indicated by optical studies. In the higher lying spin-orbit sublevel, significant lambda-doubling interactions are observed, as is found in NiH(X2Δi).

AB - Measurement of the pure rotational spectrum of NiCN in its 2Δi ground electronic state has enabled the identification of both spin-orbit components of this molecule, as well as new vibronic levels. It has confirmed the linear cyanide structure of this radical, as indicated by optical studies. In the higher lying spin-orbit sublevel, significant lambda-doubling interactions are observed, as is found in NiH(X2Δi).

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Further studies of 3d transition metal cyanides: The pure rotational spectrum of NiCN (X²Δ_i)

Abstract

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