@article{7e757b75a6ea4457a12426b2625a0279,
title = "Functionalized chalcogenide hybrid inorganic/organic polymers (CHIPs): Via inverse vulcanization of elemental sulfur and vinylanilines",
abstract = "In this report, a new class of functional chalcogenide hybrid inorganic/organic polymers (CHIPs) bearing free aryl amine groups that are amenable to post-polymerization modifications were synthesized. These functional CHIPs were synthesized via the inverse vulcanization of elemental sulfur with 4-vinylaniline without the need for functional group protection of amines. This polymer is the first example of a polysulfide or CHIP material to carry a useful primary amine functional group which can be successfully post functionalized with acid chlorides and isocyanates to improve the mechanical properties.",
author = "Yueyan Zhang and Kleine, {Tristan S.} and Carothers, {Kyle J.} and Phan, {David D.} and Glass, {Richard S.} and Mackay, {Michael E.} and Kookheon Char and Jeffrey Pyun",
note = "Funding Information: We acknowledge the NSF (DMR-1607971), Kuraray, for the support of this work. KC acknowledges the support from the NRF for the National Creative Research Initiative Center for Intelligent Hybrids (2010-0018290). D. D. P. acknowledges the NIST award 70NANB10H256 through the Center for Neutron Science at the University of Delaware. We acknowledge the University of Delaware's funding provided through the Department of Materials Science and Engineering and U.S. Army contract number W911NF-17-2-0186. S. Funding Information: We acknowledge the NSF (DMR-1607971), Kuraray, for the support of this work. KC acknowledges the support from the NRF for the National Creative Research Initiative Center for Intelligent Hybrids (2010-0018290). D. D. P. acknowledges the NIST award 70NANB10H256 through the Center for Neutron Science at the University of Delaware. We acknowledge the University of Delaware{\textquoteright}s funding provided through the Department of Materials Science and Engineering and U.S. Army contract number W911NF-17-2-0186. S. Publisher Copyright: {\textcopyright} 2018 The Royal Society of Chemistry.",
year = "2018",
month = may,
doi = "10.1039/c8py00270c",
language = "English (US)",
volume = "9",
pages = "2290--2294",
journal = "Polymer Chemistry",
issn = "1759-9954",
publisher = "Royal Society of Chemistry",
number = "17",
}