Functionalized chalcogenide hybrid inorganic/organic polymers (CHIPs): Via inverse vulcanization of elemental sulfur and vinylanilines

Yueyan Zhang; Tristan S. Kleine; Kyle J. Carothers; David D. Phan; Richard S. Glass; Michael E. Mackay; Kookheon Char; Jeffrey Pyun

doi:10.1039/c8py00270c

Functionalized chalcogenide hybrid inorganic/organic polymers (CHIPs): Via inverse vulcanization of elemental sulfur and vinylanilines

Yueyan Zhang, Tristan S. Kleine, Kyle J. Carothers, David D. Phan, Richard S. Glass, Michael E. Mackay, Kookheon Char, Jeffrey Pyun

Chemistry and Biochemistry

Research output: Contribution to journal › Article › peer-review

48 Scopus citations

Abstract

In this report, a new class of functional chalcogenide hybrid inorganic/organic polymers (CHIPs) bearing free aryl amine groups that are amenable to post-polymerization modifications were synthesized. These functional CHIPs were synthesized via the inverse vulcanization of elemental sulfur with 4-vinylaniline without the need for functional group protection of amines. This polymer is the first example of a polysulfide or CHIP material to carry a useful primary amine functional group which can be successfully post functionalized with acid chlorides and isocyanates to improve the mechanical properties.

Original language	English (US)
Pages (from-to)	2290-2294
Number of pages	5
Journal	Polymer Chemistry
Volume	9
Issue number	17
DOIs	https://doi.org/10.1039/c8py00270c
State	Published - May 2018

ASJC Scopus subject areas

Bioengineering
Biochemistry
Polymers and Plastics
Organic Chemistry

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title = "Functionalized chalcogenide hybrid inorganic/organic polymers (CHIPs): Via inverse vulcanization of elemental sulfur and vinylanilines",

abstract = "In this report, a new class of functional chalcogenide hybrid inorganic/organic polymers (CHIPs) bearing free aryl amine groups that are amenable to post-polymerization modifications were synthesized. These functional CHIPs were synthesized via the inverse vulcanization of elemental sulfur with 4-vinylaniline without the need for functional group protection of amines. This polymer is the first example of a polysulfide or CHIP material to carry a useful primary amine functional group which can be successfully post functionalized with acid chlorides and isocyanates to improve the mechanical properties.",

author = "Yueyan Zhang and Kleine, {Tristan S.} and Carothers, {Kyle J.} and Phan, {David D.} and Glass, {Richard S.} and Mackay, {Michael E.} and Kookheon Char and Jeffrey Pyun",

note = "Publisher Copyright: {\textcopyright} 2018 The Royal Society of Chemistry.",

year = "2018",

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doi = "10.1039/c8py00270c",

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T1 - Functionalized chalcogenide hybrid inorganic/organic polymers (CHIPs)

T2 - Via inverse vulcanization of elemental sulfur and vinylanilines

AU - Zhang, Yueyan

AU - Kleine, Tristan S.

AU - Carothers, Kyle J.

AU - Phan, David D.

AU - Glass, Richard S.

AU - Mackay, Michael E.

AU - Char, Kookheon

AU - Pyun, Jeffrey

PY - 2018/5

Y1 - 2018/5

N2 - In this report, a new class of functional chalcogenide hybrid inorganic/organic polymers (CHIPs) bearing free aryl amine groups that are amenable to post-polymerization modifications were synthesized. These functional CHIPs were synthesized via the inverse vulcanization of elemental sulfur with 4-vinylaniline without the need for functional group protection of amines. This polymer is the first example of a polysulfide or CHIP material to carry a useful primary amine functional group which can be successfully post functionalized with acid chlorides and isocyanates to improve the mechanical properties.

AB - In this report, a new class of functional chalcogenide hybrid inorganic/organic polymers (CHIPs) bearing free aryl amine groups that are amenable to post-polymerization modifications were synthesized. These functional CHIPs were synthesized via the inverse vulcanization of elemental sulfur with 4-vinylaniline without the need for functional group protection of amines. This polymer is the first example of a polysulfide or CHIP material to carry a useful primary amine functional group which can be successfully post functionalized with acid chlorides and isocyanates to improve the mechanical properties.

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Functionalized chalcogenide hybrid inorganic/organic polymers (CHIPs): Via inverse vulcanization of elemental sulfur and vinylanilines

Abstract

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