Functionalization of polymers prepared by ATRP using radical addition reactions

Veerle Coessens; Jeffrey Pyun; Peter J. Miller; Scott G. Gaynor; Krzysztof Matyjaszewski

doi:10.1002/(SICI)1521-3927(20000201)21:2<103::AID-MARC103>3.0.CO;2-H

Functionalization of polymers prepared by ATRP using radical addition reactions

Veerle Coessens, Jeffrey Pyun, Peter J. Miller, Scott G. Gaynor, Krzysztof Matyjaszewski

Research output: Contribution to journal › Article › peer-review

107 Scopus citations

Abstract

Low molecular weight linear poly(methyl acrylate), star and hyperbranched polymers were synthesized using atom transfer radical polymerization (ATRP) and end-functionalized using radical addition reactions. By adding allyltri-n-butylstannane at the end of the polymerization of poly(methyl acrylate), the polymer was terminated by allyl groups. When at high conversions of the acrylate monomer, allyl alcohol or 1,2-epoxy-5-hexene, monomers which are not polymerizable by ATRP, were added, alcohol and epoxy functionalities respectively were incorporated at the polymer chain end. Functionalization by radical addition reactions was demonstrated to be applicable to multi-functional polymers such as hyperbranched and star polymers.

Original language	English (US)
Pages (from-to)	103-109
Number of pages	7
Journal	Macromolecular Rapid Communications
Volume	21
Issue number	2
DOIs	https://doi.org/10.1002/(SICI)1521-3927(20000201)21:2<103::AID-MARC103>3.0.CO;2-H
State	Published - 2000

ASJC Scopus subject areas

Organic Chemistry
Polymers and Plastics
Materials Chemistry

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10.1002/(SICI)1521-3927(20000201)21:2<103::AID-MARC103>3.0.CO;2-H

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abstract = "Low molecular weight linear poly(methyl acrylate), star and hyperbranched polymers were synthesized using atom transfer radical polymerization (ATRP) and end-functionalized using radical addition reactions. By adding allyltri-n-butylstannane at the end of the polymerization of poly(methyl acrylate), the polymer was terminated by allyl groups. When at high conversions of the acrylate monomer, allyl alcohol or 1,2-epoxy-5-hexene, monomers which are not polymerizable by ATRP, were added, alcohol and epoxy functionalities respectively were incorporated at the polymer chain end. Functionalization by radical addition reactions was demonstrated to be applicable to multi-functional polymers such as hyperbranched and star polymers.",

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AU - Coessens, Veerle

AU - Pyun, Jeffrey

AU - Miller, Peter J.

AU - Gaynor, Scott G.

AU - Matyjaszewski, Krzysztof

PY - 2000

Y1 - 2000

N2 - Low molecular weight linear poly(methyl acrylate), star and hyperbranched polymers were synthesized using atom transfer radical polymerization (ATRP) and end-functionalized using radical addition reactions. By adding allyltri-n-butylstannane at the end of the polymerization of poly(methyl acrylate), the polymer was terminated by allyl groups. When at high conversions of the acrylate monomer, allyl alcohol or 1,2-epoxy-5-hexene, monomers which are not polymerizable by ATRP, were added, alcohol and epoxy functionalities respectively were incorporated at the polymer chain end. Functionalization by radical addition reactions was demonstrated to be applicable to multi-functional polymers such as hyperbranched and star polymers.

AB - Low molecular weight linear poly(methyl acrylate), star and hyperbranched polymers were synthesized using atom transfer radical polymerization (ATRP) and end-functionalized using radical addition reactions. By adding allyltri-n-butylstannane at the end of the polymerization of poly(methyl acrylate), the polymer was terminated by allyl groups. When at high conversions of the acrylate monomer, allyl alcohol or 1,2-epoxy-5-hexene, monomers which are not polymerizable by ATRP, were added, alcohol and epoxy functionalities respectively were incorporated at the polymer chain end. Functionalization by radical addition reactions was demonstrated to be applicable to multi-functional polymers such as hyperbranched and star polymers.

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Functionalization of polymers prepared by ATRP using radical addition reactions

Abstract

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