Framework solids possessing both hydrophobic and hydrophilic pores constructed by face-sharing keplerate-type heterometal-organic polyhedra

Xiang Jian Kong; Han Zhang; Hai Xia Zhao; Yan Ping Ren; La Sheng Long; Zhiping Zheng; Gary S. Nichol; Rong Bin Huang; Lan Sun Zheng

doi:10.1002/chem.200903430

Framework solids possessing both hydrophobic and hydrophilic pores constructed by face-sharing keplerate-type heterometal-organic polyhedra

Xiang Jian Kong, Han Zhang, Hai Xia Zhao, Yan Ping Ren, La Sheng Long, Zhiping Zheng, Gary S. Nichol, Rong Bin Huang, Lan Sun Zheng

Research output: Contribution to journal › Article › peer-review

20 Scopus citations

Abstract

Interesting MOPs! TWo isostructural framework structures built from novel Keplerate-type 3d-4f heterometalorganic polyhedra (HMOPs), both with hydrophilic and hydrophobic pores of nanoscopic dimensions, have been obtained. The 36-metal HMOPs display an aesthetically pleasing double-Archimedean solid structure characterized by a cuboctahedron encapsulating a rhombicuboctahedron (see figure). (Figure Presented)

Original language	English (US)
Pages (from-to)	5292-5296
Number of pages	5
Journal	Chemistry - A European Journal
Volume	16
Issue number	18
DOIs	https://doi.org/10.1002/chem.200903430
State	Published - May 10 2010
Externally published	Yes

Keywords

Cage compounds
Heterometallic complexes
Lanthanides
Metal-organic frameworks
Structure elucidation

ASJC Scopus subject areas

Catalysis
Organic Chemistry

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10.1002/chem.200903430

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title = "Framework solids possessing both hydrophobic and hydrophilic pores constructed by face-sharing keplerate-type heterometal-organic polyhedra",

abstract = "Interesting MOPs! TWo isostructural framework structures built from novel Keplerate-type 3d-4f heterometalorganic polyhedra (HMOPs), both with hydrophilic and hydrophobic pores of nanoscopic dimensions, have been obtained. The 36-metal HMOPs display an aesthetically pleasing double-Archimedean solid structure characterized by a cuboctahedron encapsulating a rhombicuboctahedron (see figure). (Figure Presented)",

keywords = "Cage compounds, Heterometallic complexes, Lanthanides, Metal-organic frameworks, Structure elucidation",

author = "Kong, {Xiang Jian} and Han Zhang and Zhao, {Hai Xia} and Ren, {Yan Ping} and Long, {La Sheng} and Zhiping Zheng and Nichol, {Gary S.} and Huang, {Rong Bin} and Zheng, {Lan Sun}",

year = "2010",

month = may,

day = "10",

doi = "10.1002/chem.200903430",

language = "English (US)",

volume = "16",

pages = "5292--5296",

journal = "Chemistry - A European Journal",

issn = "0947-6539",

publisher = "Wiley-VCH Verlag",

number = "18",

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TY - JOUR

T1 - Framework solids possessing both hydrophobic and hydrophilic pores constructed by face-sharing keplerate-type heterometal-organic polyhedra

AU - Kong, Xiang Jian

AU - Zhang, Han

AU - Zhao, Hai Xia

AU - Ren, Yan Ping

AU - Long, La Sheng

AU - Zheng, Zhiping

AU - Nichol, Gary S.

AU - Huang, Rong Bin

AU - Zheng, Lan Sun

PY - 2010/5/10

Y1 - 2010/5/10

N2 - Interesting MOPs! TWo isostructural framework structures built from novel Keplerate-type 3d-4f heterometalorganic polyhedra (HMOPs), both with hydrophilic and hydrophobic pores of nanoscopic dimensions, have been obtained. The 36-metal HMOPs display an aesthetically pleasing double-Archimedean solid structure characterized by a cuboctahedron encapsulating a rhombicuboctahedron (see figure). (Figure Presented)

AB - Interesting MOPs! TWo isostructural framework structures built from novel Keplerate-type 3d-4f heterometalorganic polyhedra (HMOPs), both with hydrophilic and hydrophobic pores of nanoscopic dimensions, have been obtained. The 36-metal HMOPs display an aesthetically pleasing double-Archimedean solid structure characterized by a cuboctahedron encapsulating a rhombicuboctahedron (see figure). (Figure Presented)

KW - Cage compounds

KW - Heterometallic complexes

KW - Lanthanides

KW - Metal-organic frameworks

KW - Structure elucidation

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U2 - 10.1002/chem.200903430

DO - 10.1002/chem.200903430

M3 - Article

C2 - 20373313

AN - SCOPUS:77951968934

SN - 0947-6539

VL - 16

SP - 5292

EP - 5296

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

IS - 18

ER -

Framework solids possessing both hydrophobic and hydrophilic pores constructed by face-sharing keplerate-type heterometal-organic polyhedra

Abstract

Keywords

ASJC Scopus subject areas

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