Fourier transform infrared spectra of the 2v2 and v2 + v4 bands of PH3

T. Tipton; J. I. Choe; S. G. Kukolich

doi:10.1021/j100399a015

Fourier transform infrared spectra of the 2v₂ and v₂ + v₄ bands of PH₃

T. Tipton
, J. I. Choe
, S. G. Kukolich

Chemistry and Biochemistry

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

The lowest-lying overtone (2v₂) and combination (v₂ + v₄) bands of phosphine have been investigated for the first time with a Fourier transform spectrometer with 0.01-cm^-1 resolution. A least-squares fit which includes Coriolis coupling parameters has been performed on both bands simultaneously. The resulting constants fit 400 transitions with a standard deviation of 0.05 cm^-1. Rotational parameters for the excited states and vibrational frequencies are obtained from the analysis.

Original language	English (US)
Pages (from-to)	1534-1537
Number of pages	4
Journal	Journal of physical chemistry
Volume	90
Issue number	8
DOIs	https://doi.org/10.1021/j100399a015
State	Published - 1986

ASJC Scopus subject areas

General Engineering
Physical and Theoretical Chemistry

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10.1021/j100399a015

Cite this

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title = "Fourier transform infrared spectra of the 2v2 and v2 + v4 bands of PH3",

abstract = "The lowest-lying overtone (2v2) and combination (v2 + v4) bands of phosphine have been investigated for the first time with a Fourier transform spectrometer with 0.01-cm-1 resolution. A least-squares fit which includes Coriolis coupling parameters has been performed on both bands simultaneously. The resulting constants fit 400 transitions with a standard deviation of 0.05 cm-1. Rotational parameters for the excited states and vibrational frequencies are obtained from the analysis.",

author = "T. Tipton and Choe, \{J. I.\} and Kukolich, \{S. G.\}",

year = "1986",

doi = "10.1021/j100399a015",

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volume = "90",

pages = "1534--1537",

journal = "Journal of physical chemistry",

issn = "0022-3654",

publisher = "American Chemical Society",

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T1 - Fourier transform infrared spectra of the 2v2 and v2 + v4 bands of PH3

AU - Tipton, T.

AU - Choe, J. I.

AU - Kukolich, S. G.

PY - 1986

Y1 - 1986

N2 - The lowest-lying overtone (2v2) and combination (v2 + v4) bands of phosphine have been investigated for the first time with a Fourier transform spectrometer with 0.01-cm-1 resolution. A least-squares fit which includes Coriolis coupling parameters has been performed on both bands simultaneously. The resulting constants fit 400 transitions with a standard deviation of 0.05 cm-1. Rotational parameters for the excited states and vibrational frequencies are obtained from the analysis.

AB - The lowest-lying overtone (2v2) and combination (v2 + v4) bands of phosphine have been investigated for the first time with a Fourier transform spectrometer with 0.01-cm-1 resolution. A least-squares fit which includes Coriolis coupling parameters has been performed on both bands simultaneously. The resulting constants fit 400 transitions with a standard deviation of 0.05 cm-1. Rotational parameters for the excited states and vibrational frequencies are obtained from the analysis.

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UR - https://www.scopus.com/pages/publications/0041341815#tab=citedBy

U2 - 10.1021/j100399a015

DO - 10.1021/j100399a015

M3 - Article

AN - SCOPUS:0041341815

SN - 0022-3654

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JO - Journal of physical chemistry

JF - Journal of physical chemistry

IS - 8

ER -

Fourier transform infrared spectra of the 2v₂ and v₂ + v₄ bands of PH₃

Abstract

ASJC Scopus subject areas

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