@article{4f204de5ff9148d9b84a44105b749995,
title = "Formic Acid Dehydrogenation for Hydrogen Production Promoted by Grubbs and Hoveyda-Grubbs Catalysts†",
abstract = "In this work, we screened three Grubbs catalysts and two Hoveyda-Grubbs catalysts for the production of H2 by dehydrogenation of formic acid (FA). The best results were achieved with the use of a first-generation Hoveyda-Grubbs catalyst. With a catalyst loading of mere 0.5 μmol, a maximum TON of 36356 was obtained within 3 h. Two key intermediates were identified by using 1H NMR and high-resolution electrospray ionization mass spectroscopy (HRESI-MS), based on which a mechanism possibly responsible for the observed catalysis was proposed.",
keywords = "Dehydrogenation, Formic acid, Grubbs and Hoveyda-Grubbs catalysts, Hydrogen, Ruthenium",
author = "Qian Wang and Yihao Xia and Fanrui Cheng and Zhijian Chen and Yifan Wang and Xiaofei Zhu and Lei Qin and Zhiping Zheng",
note = "Funding Information: Financial support by start‐up fund from SUSTech (Nos. Y01216127 and Y01216227, ZZ), the Distinguished Expert Fund from Nanshan District of Shenzhen (No. K19219502, ZZ), the China Postdoctoral Science Foundation (No. 2018M640226, LQ), the SUSTech Presidential Postdoctoral Fellowship (LQ), the Basic and Applied Basic Research Programs of Guangdong Province (No. 2020A1515110990, LQ), the Post‐doctorate Scientific Research Fund for staying (coming to) Shenzhen (K21217515, LQ), the Jilin Provincial Science Research Foundation of China (No. 20200403154SF) and Special Funds for the Cultivation of Guangdong College Students{\textquoteright} Scientific and Technological Innovation (“Climbing Program” Special Funds, pdjh2020c0034) is acknowledged. This work was also partly sponsored by Guangdong Provincial Key Laboratory of Catalysis (No. 2020B121201002) and the Shenzhen Nobel Prize Scientists Laboratory Project (No. C17783101). Funding Information: Financial support by start-up fund from SUSTech (Nos. Y01216127 and Y01216227, ZZ), the Distinguished Expert Fund from Nanshan District of Shenzhen (No. K19219502, ZZ), the China Postdoctoral Science Foundation (No. 2018M640226, LQ), the SUSTech Presidential Postdoctoral Fellowship (LQ), the Basic and Applied Basic Research Programs of Guangdong Province (No. 2020A1515110990, LQ), the Post-doctorate Scientific Research Fund for staying (coming to) Shenzhen (K21217515, LQ), the Jilin Provincial Science Research Foundation of China (No. 20200403154SF) and Special Funds for the Cultivation of Guangdong College Students? Scientific and Technological Innovation (?Climbing Program? Special Funds, pdjh2020c0034) is acknowledged. This work was also partly sponsored by Guangdong Provincial Key Laboratory of Catalysis (No. 2020B121201002) and the Shenzhen Nobel Prize Scientists Laboratory Project (No. C17783101). Publisher Copyright: {\textcopyright} 2021 SIOC, CAS, Shanghai and Wiley-VCH GmbH",
year = "2021",
month = aug,
doi = "10.1002/cjoc.202000749",
language = "English (US)",
volume = "39",
pages = "2201--2206",
journal = "Chinese Journal of Chemistry",
issn = "1001-604X",
publisher = "Shanghai Institute of Organic Chemistry",
number = "8",
}