Abstract
The equilibria between the five- and six-coordinate species of alkylcobinamide and cobalamin (base-off) have been studied using high-pressure spectroscopic techniques. The addition of a water molecule to the five-coordinate complex is accompanied by a volume decrease of 12 cm3·mol-1.
Original language | English (US) |
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Pages (from-to) | 580-583 |
Number of pages | 4 |
Journal | European Journal of Inorganic Chemistry |
Issue number | 3 |
DOIs | |
State | Published - 2002 |
Keywords
- Adduct formation
- Cobalt
- Equilibrium
- High-pressure chemistry
- Kinetics
- Ligand substitution
- Reaction mechanisms
ASJC Scopus subject areas
- Inorganic Chemistry