TY - JOUR
T1 - Environmentally Friendly Methylcellulose Blend Binder for Hydrophobic Dust Control
AU - Lee, Taehee
AU - Camp, Christopher P.
AU - Kim, Bumjoon
AU - Kim, Minkyu
N1 - Funding Information:
This work was supported by the University of Arizona. We appreciate Dr. Sungnam Chun at Korea Electric Power Corporation Research Institute (KEPRI) for providing coal samples and for the helpful discussions. We also thank Dr. Dongkyun Kang in the Department of Biomedical Engineering at the University of Arizona for the discussion of microscopy.
Publisher Copyright:
© 2022 American Chemical Society.
PY - 2022/2/11
Y1 - 2022/2/11
N2 - A critical demand has existed for the past two decades to develop environmentally friendly, naturally degradable, and cost-effective materials to mitigate hydrophobic pollutants that directly endanger the environment and public health. Here, a newly developed methylcellulose blend (MCB), composed of hydroxypropyl methylcellulose (HPMC) and liquid amphiphilic polymer (LAP), synergistically enhanced the wettability of hydrophobic particles as a water additive and increased the average particle size as a binder. This observation was leveraged to evaluate MCB-based dust controlling materials via air filtering performance, mechanical vibration, and wind erosion tests. The filtration efficiency of filter membranes was enhanced up to 95% by a spray coating of MCB, while maintaining the same breathability as the untreated membrane. MCB sprayed on the surface of dust sources reduced generation of inhalable dust of <10 μm diameter up to 90% against a stream of air at 25 m/s compared to water treatment as a control. The effectiveness was maximal at 0.1% (w/v) HPMC and LAP due to molecular interactions between the MCB and hydrophobic dust at certain MCB constituent ratios. Altogether, the synergistic wettability and adhesiveness of the MCB provide the fundamental scientific concept and the technological progress to develop environmentally friendly formulations for advanced dust control technology.
AB - A critical demand has existed for the past two decades to develop environmentally friendly, naturally degradable, and cost-effective materials to mitigate hydrophobic pollutants that directly endanger the environment and public health. Here, a newly developed methylcellulose blend (MCB), composed of hydroxypropyl methylcellulose (HPMC) and liquid amphiphilic polymer (LAP), synergistically enhanced the wettability of hydrophobic particles as a water additive and increased the average particle size as a binder. This observation was leveraged to evaluate MCB-based dust controlling materials via air filtering performance, mechanical vibration, and wind erosion tests. The filtration efficiency of filter membranes was enhanced up to 95% by a spray coating of MCB, while maintaining the same breathability as the untreated membrane. MCB sprayed on the surface of dust sources reduced generation of inhalable dust of <10 μm diameter up to 90% against a stream of air at 25 m/s compared to water treatment as a control. The effectiveness was maximal at 0.1% (w/v) HPMC and LAP due to molecular interactions between the MCB and hydrophobic dust at certain MCB constituent ratios. Altogether, the synergistic wettability and adhesiveness of the MCB provide the fundamental scientific concept and the technological progress to develop environmentally friendly formulations for advanced dust control technology.
KW - air filter
KW - dust suppressant
KW - hydrophobic dust
KW - hydroxypropyl methylcellulose
KW - liquid amphiphilic polymer
KW - methylcellulose blend
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U2 - 10.1021/acsapm.1c01887
DO - 10.1021/acsapm.1c01887
M3 - Article
AN - SCOPUS:85124009471
SN - 2637-6105
VL - 4
SP - 1512
EP - 1522
JO - ACS Applied Polymer Materials
JF - ACS Applied Polymer Materials
IS - 2
ER -