Electrochemical study of a polypyrrole film/decanethiol self-assembled monolayer on a gold electrode

Jun Wang; Baizhao Zeng; Cheng Fang; Fei He; Xingyao Zhou

doi:10.1002/(SICI)1521-4109(199912)11:18<1345::AID-ELAN1345>3.0.CO;2-T

Electrochemical study of a polypyrrole film/decanethiol self-assembled monolayer on a gold electrode

Jun Wang, Baizhao Zeng, Cheng Fang, Fei He, Xingyao Zhou

Research output: Contribution to journal › Article › peer-review

18 Scopus citations

Abstract

Cyclic voltammetry and chronoamperometry were used to study the deposition of polypyrrole on a decanethiol self-assembled monolayer modified gold electrode (PPY/SAM/Au). The voltammetric behavior of the PPY/SAM film was investigated in the presence of several different electrolytes. It is found that the SAM shows great influence on the nucleation and growth of the PPY film The reaction of the SAM and the anions causes the different voltammetric behavior of the polymerization of pyrrole on the modified electrode Chronoamperometry shows the nucleation and growth of the PPY is initially inhibited but followed by a rapid increase. The SAM also influences electrochemical behavior of PPY film. Experiments show that the SAM can greatly depress the diffusion of anions in the PPY film and minimize the background capacitance current.

Original language	English (US)
Pages (from-to)	1345-1349
Number of pages	5
Journal	Electroanalysis
Volume	11
Issue number	18
DOIs	https://doi.org/10.1002/(SICI)1521-4109(199912)11:18<1345::AID-ELAN1345>3.0.CO;2-T
State	Published - Dec 1999
Externally published	Yes

Keywords

Au electrode
Chronoamperometry
Cyclic voltammetry
Decanethiol
Polypyrrole film
Self-assembled monolayer

ASJC Scopus subject areas

Analytical Chemistry
Electrochemistry

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10.1002/(SICI)1521-4109(199912)11:18<1345::AID-ELAN1345>3.0.CO;2-T

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@article{c794a139480840e4a8658fbce5148155,

title = "Electrochemical study of a polypyrrole film/decanethiol self-assembled monolayer on a gold electrode",

abstract = "Cyclic voltammetry and chronoamperometry were used to study the deposition of polypyrrole on a decanethiol self-assembled monolayer modified gold electrode (PPY/SAM/Au). The voltammetric behavior of the PPY/SAM film was investigated in the presence of several different electrolytes. It is found that the SAM shows great influence on the nucleation and growth of the PPY film The reaction of the SAM and the anions causes the different voltammetric behavior of the polymerization of pyrrole on the modified electrode Chronoamperometry shows the nucleation and growth of the PPY is initially inhibited but followed by a rapid increase. The SAM also influences electrochemical behavior of PPY film. Experiments show that the SAM can greatly depress the diffusion of anions in the PPY film and minimize the background capacitance current.",

keywords = "Au electrode, Chronoamperometry, Cyclic voltammetry, Decanethiol, Polypyrrole film, Self-assembled monolayer",

author = "Jun Wang and Baizhao Zeng and Cheng Fang and Fei He and Xingyao Zhou",

year = "1999",

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doi = "10.1002/(SICI)1521-4109(199912)11:18<1345::AID-ELAN1345>3.0.CO;2-T",

language = "English (US)",

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TY - JOUR

T1 - Electrochemical study of a polypyrrole film/decanethiol self-assembled monolayer on a gold electrode

AU - Wang, Jun

AU - Zeng, Baizhao

AU - Fang, Cheng

AU - He, Fei

AU - Zhou, Xingyao

PY - 1999/12

Y1 - 1999/12

N2 - Cyclic voltammetry and chronoamperometry were used to study the deposition of polypyrrole on a decanethiol self-assembled monolayer modified gold electrode (PPY/SAM/Au). The voltammetric behavior of the PPY/SAM film was investigated in the presence of several different electrolytes. It is found that the SAM shows great influence on the nucleation and growth of the PPY film The reaction of the SAM and the anions causes the different voltammetric behavior of the polymerization of pyrrole on the modified electrode Chronoamperometry shows the nucleation and growth of the PPY is initially inhibited but followed by a rapid increase. The SAM also influences electrochemical behavior of PPY film. Experiments show that the SAM can greatly depress the diffusion of anions in the PPY film and minimize the background capacitance current.

AB - Cyclic voltammetry and chronoamperometry were used to study the deposition of polypyrrole on a decanethiol self-assembled monolayer modified gold electrode (PPY/SAM/Au). The voltammetric behavior of the PPY/SAM film was investigated in the presence of several different electrolytes. It is found that the SAM shows great influence on the nucleation and growth of the PPY film The reaction of the SAM and the anions causes the different voltammetric behavior of the polymerization of pyrrole on the modified electrode Chronoamperometry shows the nucleation and growth of the PPY is initially inhibited but followed by a rapid increase. The SAM also influences electrochemical behavior of PPY film. Experiments show that the SAM can greatly depress the diffusion of anions in the PPY film and minimize the background capacitance current.

KW - Au electrode

KW - Chronoamperometry

KW - Cyclic voltammetry

KW - Decanethiol

KW - Polypyrrole film

KW - Self-assembled monolayer

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SN - 1040-0397

VL - 11

SP - 1345

EP - 1349

JO - Electroanalysis

JF - Electroanalysis

IS - 18

ER -

Electrochemical study of a polypyrrole film/decanethiol self-assembled monolayer on a gold electrode

Abstract

Keywords

ASJC Scopus subject areas

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