Efficient preparation of trans-α,β-unsaturated aldehydes from saturated aldehydes by oxidative enamine catalysis

Shilei Zhang; Hexin Xie; Aiguo Song; Deyan Wu; Jin Zhu; Sihan Zhao; Jian Li; Xinhong Yu; Wei Wang

doi:10.1007/s11426-011-4432-6

Efficient preparation of trans-α,β-unsaturated aldehydes from saturated aldehydes by oxidative enamine catalysis

Shilei Zhang
, Hexin Xie
, Aiguo Song
, Deyan Wu
, Jin Zhu
, Sihan Zhao
, Jian Li
, Xinhong Yu
, Wei Wang

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

A mild and highly efficient amine-catalyzed, IBX-mediated oxidation of aldehydes to (E) selective α,β-unsaturated aldehydes has been achieved in good yields. The process features a new oxidation of enamines to iminium ions in a catalytic fashion.

Original language	English (US)
Pages (from-to)	1932-1936
Number of pages	5
Journal	Science China Chemistry
Volume	54
Issue number	12
DOIs	https://doi.org/10.1007/s11426-011-4432-6
State	Published - Dec 2011
Externally published	Yes

Keywords

IBX
aldehydes
enals
enamines
oxidative enamine catalysis

ASJC Scopus subject areas

General Chemistry

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10.1007/s11426-011-4432-6

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title = "Efficient preparation of trans-α,β-unsaturated aldehydes from saturated aldehydes by oxidative enamine catalysis",

abstract = "A mild and highly efficient amine-catalyzed, IBX-mediated oxidation of aldehydes to (E) selective α,β-unsaturated aldehydes has been achieved in good yields. The process features a new oxidation of enamines to iminium ions in a catalytic fashion.",

keywords = "IBX, aldehydes, enals, enamines, oxidative enamine catalysis",

author = "Shilei Zhang and Hexin Xie and Aiguo Song and Deyan Wu and Jin Zhu and Sihan Zhao and Jian Li and Xinhong Yu and Wei Wang",

note = "Funding Information: We are grateful for the financial support from the National Science Foundation (CHE-1057569, W. W.) and the China 111 Project (B07023, J. L. and W. W.), the National Natural Science Foundation of China (20972051, X. Y.-H.), and the Science and Technology Commission of Shanghai Municipality (08430703900 \& 08431901800, X. Y.-H.).",

year = "2011",

month = dec,

doi = "10.1007/s11426-011-4432-6",

language = "English (US)",

volume = "54",

pages = "1932--1936",

journal = "Science China Chemistry",

issn = "1674-7291",

publisher = "Science China Press",

number = "12",

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TY - JOUR

T1 - Efficient preparation of trans-α,β-unsaturated aldehydes from saturated aldehydes by oxidative enamine catalysis

AU - Zhang, Shilei

AU - Xie, Hexin

AU - Song, Aiguo

AU - Wu, Deyan

AU - Zhu, Jin

AU - Zhao, Sihan

AU - Li, Jian

AU - Yu, Xinhong

AU - Wang, Wei

N1 - Funding Information: We are grateful for the financial support from the National Science Foundation (CHE-1057569, W. W.) and the China 111 Project (B07023, J. L. and W. W.), the National Natural Science Foundation of China (20972051, X. Y.-H.), and the Science and Technology Commission of Shanghai Municipality (08430703900 & 08431901800, X. Y.-H.).

PY - 2011/12

Y1 - 2011/12

N2 - A mild and highly efficient amine-catalyzed, IBX-mediated oxidation of aldehydes to (E) selective α,β-unsaturated aldehydes has been achieved in good yields. The process features a new oxidation of enamines to iminium ions in a catalytic fashion.

AB - A mild and highly efficient amine-catalyzed, IBX-mediated oxidation of aldehydes to (E) selective α,β-unsaturated aldehydes has been achieved in good yields. The process features a new oxidation of enamines to iminium ions in a catalytic fashion.

KW - IBX

KW - aldehydes

KW - enals

KW - enamines

KW - oxidative enamine catalysis

UR - https://www.scopus.com/pages/publications/84856214377

UR - https://www.scopus.com/pages/publications/84856214377#tab=citedBy

U2 - 10.1007/s11426-011-4432-6

DO - 10.1007/s11426-011-4432-6

M3 - Article

AN - SCOPUS:84856214377

SN - 1674-7291

VL - 54

SP - 1932

EP - 1936

JO - Science China Chemistry

JF - Science China Chemistry

IS - 12

ER -

Efficient preparation of trans-α,β-unsaturated aldehydes from saturated aldehydes by oxidative enamine catalysis

Abstract

Keywords

ASJC Scopus subject areas

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