Effect of Zr/Ti ratio on the fatigue and retention behavior of sol-gel derived PZT films

G. Teowee; M. Boulton; M. N. Orr; C. D. Baertlein; R. K. Wade; D. P. Birnie; D. R. Uhlmann

doi:10.1557/proc-310-423

Effect of Zr/Ti ratio on the fatigue and retention behavior of sol-gel derived PZT films

G. Teowee, M. Boulton, M. N. Orr, C. D. Baertlein, R. K. Wade, D. P. Birnie, D. R. Uhlmann

Research output: Contribution to journal › Conference article › peer-review

7 Scopus citations

Abstract

A series of sol-gel derived PZT films with various Zr/Ti ratios-namely PT, 0/100 -20/80, 35/65, 53/47, 65/35 80/20, 94/6 and PZ, 100/0 -were prepared on platinized Si wafers. Excess PbO was added to the precursor chemistries to compensate for eventual PbO loss and also to aid in obtaining the desired perovskite phase. It was found that the phase assembly, namely the presence of tetragonal or rhombohedral perovskite phases, plays an important role in determining the fatigue and retention behavioral. PT-rich (or tetragonal) films offer better retention characteristics than those observed in PZ-rich (or rhombohedral) or PZT 53/47 films. Films with PZ-rich compositions tend to exhibit superior fatigue behavior compared with PT-rich films.

Original language	English (US)
Pages (from-to)	423-428
Number of pages	6
Journal	Materials Research Society Symposium - Proceedings
Volume	310
DOIs	https://doi.org/10.1557/proc-310-423
State	Published - 1993
Externally published	Yes
Event	Proceedings of the 1993 Spring Meeting of the Materials Research Society - San Francisco, CA, USA Duration: Apr 14 1993 → Apr 16 1993

ASJC Scopus subject areas

General Materials Science
Condensed Matter Physics
Mechanics of Materials
Mechanical Engineering

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@article{e523eb87aa2c4fe5ba2de4f52da61220,

title = "Effect of Zr/Ti ratio on the fatigue and retention behavior of sol-gel derived PZT films",

abstract = "A series of sol-gel derived PZT films with various Zr/Ti ratios-namely PT, 0/100 -20/80, 35/65, 53/47, 65/35 80/20, 94/6 and PZ, 100/0 -were prepared on platinized Si wafers. Excess PbO was added to the precursor chemistries to compensate for eventual PbO loss and also to aid in obtaining the desired perovskite phase. It was found that the phase assembly, namely the presence of tetragonal or rhombohedral perovskite phases, plays an important role in determining the fatigue and retention behavioral. PT-rich (or tetragonal) films offer better retention characteristics than those observed in PZ-rich (or rhombohedral) or PZT 53/47 films. Films with PZ-rich compositions tend to exhibit superior fatigue behavior compared with PT-rich films.",

author = "G. Teowee and M. Boulton and Orr, {M. N.} and Baertlein, {C. D.} and Wade, {R. K.} and Birnie, {D. P.} and Uhlmann, {D. R.}",

year = "1993",

doi = "10.1557/proc-310-423",

language = "English (US)",

volume = "310",

pages = "423--428",

journal = "Materials Research Society Symposium - Proceedings",

issn = "0272-9172",

publisher = "Materials Research Society",

note = "Proceedings of the 1993 Spring Meeting of the Materials Research Society ; Conference date: 14-04-1993 Through 16-04-1993",

}

TY - JOUR

T1 - Effect of Zr/Ti ratio on the fatigue and retention behavior of sol-gel derived PZT films

AU - Teowee, G.

AU - Boulton, M.

AU - Orr, M. N.

AU - Baertlein, C. D.

AU - Wade, R. K.

AU - Birnie, D. P.

AU - Uhlmann, D. R.

PY - 1993

Y1 - 1993

N2 - A series of sol-gel derived PZT films with various Zr/Ti ratios-namely PT, 0/100 -20/80, 35/65, 53/47, 65/35 80/20, 94/6 and PZ, 100/0 -were prepared on platinized Si wafers. Excess PbO was added to the precursor chemistries to compensate for eventual PbO loss and also to aid in obtaining the desired perovskite phase. It was found that the phase assembly, namely the presence of tetragonal or rhombohedral perovskite phases, plays an important role in determining the fatigue and retention behavioral. PT-rich (or tetragonal) films offer better retention characteristics than those observed in PZ-rich (or rhombohedral) or PZT 53/47 films. Films with PZ-rich compositions tend to exhibit superior fatigue behavior compared with PT-rich films.

AB - A series of sol-gel derived PZT films with various Zr/Ti ratios-namely PT, 0/100 -20/80, 35/65, 53/47, 65/35 80/20, 94/6 and PZ, 100/0 -were prepared on platinized Si wafers. Excess PbO was added to the precursor chemistries to compensate for eventual PbO loss and also to aid in obtaining the desired perovskite phase. It was found that the phase assembly, namely the presence of tetragonal or rhombohedral perovskite phases, plays an important role in determining the fatigue and retention behavioral. PT-rich (or tetragonal) films offer better retention characteristics than those observed in PZ-rich (or rhombohedral) or PZT 53/47 films. Films with PZ-rich compositions tend to exhibit superior fatigue behavior compared with PT-rich films.

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DO - 10.1557/proc-310-423

M3 - Conference article

AN - SCOPUS:0027839927

SN - 0272-9172

VL - 310

SP - 423

EP - 428

JO - Materials Research Society Symposium - Proceedings

JF - Materials Research Society Symposium - Proceedings

T2 - Proceedings of the 1993 Spring Meeting of the Materials Research Society

Y2 - 14 April 1993 through 16 April 1993

ER -

Effect of Zr/Ti ratio on the fatigue and retention behavior of sol-gel derived PZT films

Abstract

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