Effect of pH on the gelation time of hexylene-bridged polysilsesquioxanes

Douglas A. Loy; Brian Mather; Andrei R. Straumanis; Colleen Baugher; Duane A. Schneider; Arturo Sanchez; Kenneth J. Shea

doi:10.1021/cm0498640

Effect of pH on the gelation time of hexylene-bridged polysilsesquioxanes

Douglas A. Loy
, Brian Mather
, Andrei R. Straumanis
, Colleen Baugher
, Duane A. Schneider
, Arturo Sanchez
, Kenneth J. Shea

Research output: Contribution to journal › Article › peer-review

34 Scopus citations

Abstract

The effect of pH on the gelation time of hexylene-bridged polysilsesquioxanes was determined with the sol-gel polymerization of 1,6-bis(trimethoxysilyl)hexane (1) in methanol. Gel times formed a crude bell curve plotted against pH with the longest gel times of 660 h near pH 5. This represents the first systematic study of the effects of pH on the gelation of polysilses-quioxanes.

Original language	English (US)
Pages (from-to)	2041-2043
Number of pages	3
Journal	Chemistry of Materials
Volume	16
Issue number	11
DOIs	https://doi.org/10.1021/cm0498640
State	Published - Jun 1 2004
Externally published	Yes

ASJC Scopus subject areas

General Chemistry
General Chemical Engineering
Materials Chemistry

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10.1021/cm0498640

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abstract = "The effect of pH on the gelation time of hexylene-bridged polysilsesquioxanes was determined with the sol-gel polymerization of 1,6-bis(trimethoxysilyl)hexane (1) in methanol. Gel times formed a crude bell curve plotted against pH with the longest gel times of 660 h near pH 5. This represents the first systematic study of the effects of pH on the gelation of polysilses-quioxanes.",

author = "Loy, \{Douglas A.\} and Brian Mather and Straumanis, \{Andrei R.\} and Colleen Baugher and Schneider, \{Duane A.\} and Arturo Sanchez and Shea, \{Kenneth J.\}",

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doi = "10.1021/cm0498640",

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T1 - Effect of pH on the gelation time of hexylene-bridged polysilsesquioxanes

AU - Loy, Douglas A.

AU - Mather, Brian

AU - Straumanis, Andrei R.

AU - Baugher, Colleen

AU - Schneider, Duane A.

AU - Sanchez, Arturo

AU - Shea, Kenneth J.

PY - 2004/6/1

Y1 - 2004/6/1

N2 - The effect of pH on the gelation time of hexylene-bridged polysilsesquioxanes was determined with the sol-gel polymerization of 1,6-bis(trimethoxysilyl)hexane (1) in methanol. Gel times formed a crude bell curve plotted against pH with the longest gel times of 660 h near pH 5. This represents the first systematic study of the effects of pH on the gelation of polysilses-quioxanes.

AB - The effect of pH on the gelation time of hexylene-bridged polysilsesquioxanes was determined with the sol-gel polymerization of 1,6-bis(trimethoxysilyl)hexane (1) in methanol. Gel times formed a crude bell curve plotted against pH with the longest gel times of 660 h near pH 5. This represents the first systematic study of the effects of pH on the gelation of polysilses-quioxanes.

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UR - https://www.scopus.com/pages/publications/2542465862#tab=citedBy

U2 - 10.1021/cm0498640

DO - 10.1021/cm0498640

M3 - Article

AN - SCOPUS:2542465862

SN - 0897-4756

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JO - Chemistry of Materials

JF - Chemistry of Materials

IS - 11

ER -

Effect of pH on the gelation time of hexylene-bridged polysilsesquioxanes

Abstract

ASJC Scopus subject areas

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