TY - JOUR
T1 - Effect of gypsum on transport of IMX-104 constituents in overland flow under simulated rainfall
AU - Polyakov, Viktor
AU - Beal, Samuel
AU - Meding, Stephen Mercer
AU - Dontsova, Katerina
N1 - Publisher Copyright:
© 2024 The Author(s). Journal of Environmental Quality published by Wiley Periodicals LLC on behalf of American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America.
PY - 2025/1/1
Y1 - 2025/1/1
N2 - Residue of energetic formulations, which is deposited on military training grounds following incomplete detonation, poses biotic hazards. This residue can be transported off-site, adsorb to soil clays and organic matter, transform or degrade, or taken up by plants and animals. Its harmful effects can be mitigated by localizing the energetics at the site of initial deposition using soil amendments and allowing them to bio- and photodegrade in situ. Small plots with coarse loamy soil were used to study the effect of gypsum (CaSO4·2H2O) on transport and redistribution under simulated rainfall of various sizes of insensitive munition explosive (IMX)-104 particles, which consist of 3-nitro-1,2,4-triazol-5-one (NTO), 2,4-dinitroanisole (DNAN), hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX), and octahydro-1,3,5,7-tertranitro-1,3,5,7-tetrazocine (HMX). The addition of gypsum more than doubled infiltration and decreased sediment loss by 16% compared to the control. The post-rainfall mass balance of IMX-104 in the order from greater to smaller pools was as follows: (1) soil surface retention, (2) off-site loss to overland flow, and (3) sub-surface infiltration. Overall, the application of gypsum significantly decreased concentration and the total mass loss of dissolved DNAN, RDX, and HMX in surface runoff. In addition, gypsum significantly decreased (for NTO, DNAN, and HMX) or delayed (for NTO, DNAN, RDX, and HMX) the peak discharge of <2 mm particulate energetics. The infiltration of NTO in the gypsum treatment was fivefold greater than in the control. Moreover, DNAN and RDX were also present in infiltration, while in the gypsum-free control none were found. Gypsum shifted the total mass balance of energetics toward subsurface flow. This study indicates that gypsum may decrease off-site transport of energetic constituents in the soils that are subject to surface sealing.
AB - Residue of energetic formulations, which is deposited on military training grounds following incomplete detonation, poses biotic hazards. This residue can be transported off-site, adsorb to soil clays and organic matter, transform or degrade, or taken up by plants and animals. Its harmful effects can be mitigated by localizing the energetics at the site of initial deposition using soil amendments and allowing them to bio- and photodegrade in situ. Small plots with coarse loamy soil were used to study the effect of gypsum (CaSO4·2H2O) on transport and redistribution under simulated rainfall of various sizes of insensitive munition explosive (IMX)-104 particles, which consist of 3-nitro-1,2,4-triazol-5-one (NTO), 2,4-dinitroanisole (DNAN), hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX), and octahydro-1,3,5,7-tertranitro-1,3,5,7-tetrazocine (HMX). The addition of gypsum more than doubled infiltration and decreased sediment loss by 16% compared to the control. The post-rainfall mass balance of IMX-104 in the order from greater to smaller pools was as follows: (1) soil surface retention, (2) off-site loss to overland flow, and (3) sub-surface infiltration. Overall, the application of gypsum significantly decreased concentration and the total mass loss of dissolved DNAN, RDX, and HMX in surface runoff. In addition, gypsum significantly decreased (for NTO, DNAN, and HMX) or delayed (for NTO, DNAN, RDX, and HMX) the peak discharge of <2 mm particulate energetics. The infiltration of NTO in the gypsum treatment was fivefold greater than in the control. Moreover, DNAN and RDX were also present in infiltration, while in the gypsum-free control none were found. Gypsum shifted the total mass balance of energetics toward subsurface flow. This study indicates that gypsum may decrease off-site transport of energetic constituents in the soils that are subject to surface sealing.
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U2 - 10.1002/jeq2.20652
DO - 10.1002/jeq2.20652
M3 - Article
AN - SCOPUS:85208939008
SN - 0047-2425
VL - 54
SP - 191
EP - 203
JO - Journal of Environmental Quality
JF - Journal of Environmental Quality
IS - 1
ER -