TY - JOUR
T1 - Dissolution behavior of kaolinitic tropical soils
AU - Chorover, Jon
AU - Sposito, Garrison
N1 - Funding Information:
of the present study. An earlier version of the manuscript was greatly improved by the thoughtful comments of Dr. Susan Carroll and two anonymous reviewers. l%anks also to Terri DeLuca and Darlene Berry for excellent typing of the manuscript. The research reported in this paper was supported in part by NSF grant no. EAR 92-21258 and the Keamey Foundation of Soil Science.
PY - 1995/8
Y1 - 1995/8
N2 - Batch experiments at controlled pH and ionic strength were conducted with representative kaolinitic soils from Brazil to investigate their short-time dissolution behavior. The release of Al and Fe from the soils showed similar pH dependence, exhibiting a minimum value (p.m.d.) just above the point of zero net charge for the soils. Both Al and Fe release rates below the p.m.d. were correlated positively with soluble organic C, proton concentration, and net proton surface charge, the last two relationships being power-law functions similar to those observed for the dissolution rates of specimen metal oxides and aluminosilicates. Below the p.m.d., release of Si from the soils exhibited a pH dependence very much like that observed for specimen kaolinites and the molar ratios, Si Al and Fe Al released, were smaller than 1.0, probably because of the rapid solubilization of organic Al forms. Above the p.m.d., colloidal dispersion occurred and Al, Si, and Fe were released in both dissolved and microparticulate forms.
AB - Batch experiments at controlled pH and ionic strength were conducted with representative kaolinitic soils from Brazil to investigate their short-time dissolution behavior. The release of Al and Fe from the soils showed similar pH dependence, exhibiting a minimum value (p.m.d.) just above the point of zero net charge for the soils. Both Al and Fe release rates below the p.m.d. were correlated positively with soluble organic C, proton concentration, and net proton surface charge, the last two relationships being power-law functions similar to those observed for the dissolution rates of specimen metal oxides and aluminosilicates. Below the p.m.d., release of Si from the soils exhibited a pH dependence very much like that observed for specimen kaolinites and the molar ratios, Si Al and Fe Al released, were smaller than 1.0, probably because of the rapid solubilization of organic Al forms. Above the p.m.d., colloidal dispersion occurred and Al, Si, and Fe were released in both dissolved and microparticulate forms.
UR - http://www.scopus.com/inward/record.url?scp=0029472332&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0029472332&partnerID=8YFLogxK
U2 - 10.1016/0016-7037(95)00200-J
DO - 10.1016/0016-7037(95)00200-J
M3 - Article
AN - SCOPUS:0029472332
VL - 59
SP - 3109
EP - 3121
JO - Geochmica et Cosmochimica Acta
JF - Geochmica et Cosmochimica Acta
SN - 0016-7037
IS - 15
ER -