Direct observation of rotational energy transfer in ammonia by time-resolved infrared-microwave double resonance

J. M. Levy; J. H.S. Wang; S. G. Kukolich; J. I. Steinfeld

doi:10.1016/0009-2614(73)80318-5

Direct observation of rotational energy transfer in ammonia by time-resolved infrared-microwave double resonance

J. M. Levy
, J. H.S. Wang
, S. G. Kukolich
, J. I. Steinfeld

Research output: Contribution to journal › Article › peer-review

23 Scopus citations

Abstract

An N₂O laser is used to pump the ground vibrational state (8,7) inversion doublet of ¹⁴NH₃ while simultaneously monitoring other ground state doublets. Time-resolved rotational energy transfer signals are observed in accordance with known selection values. Absolute rates of rotational energy transfer processes are estimated.

Original language	English (US)
Pages (from-to)	598-602
Number of pages	5
Journal	Chemical Physics Letters
Volume	21
Issue number	3
DOIs	https://doi.org/10.1016/0009-2614(73)80318-5
State	Published - Sep 1 1973
Externally published	Yes

ASJC Scopus subject areas

General Physics and Astronomy
Physical and Theoretical Chemistry

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10.1016/0009-2614(73)80318-5

Cite this

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title = "Direct observation of rotational energy transfer in ammonia by time-resolved infrared-microwave double resonance",

abstract = "An N2O laser is used to pump the ground vibrational state (8,7) inversion doublet of 14NH3 while simultaneously monitoring other ground state doublets. Time-resolved rotational energy transfer signals are observed in accordance with known selection values. Absolute rates of rotational energy transfer processes are estimated.",

author = "Levy, \{J. M.\} and Wang, \{J. H.S.\} and Kukolich, \{S. G.\} and Steinfeld, \{J. I.\}",

note = "Funding Information: * Work supported by Air Force Office of Scientific under grant AFOSR-7 l-2032.",

year = "1973",

month = sep,

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doi = "10.1016/0009-2614(73)80318-5",

language = "English (US)",

volume = "21",

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journal = "Chemical Physics Letters",

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T1 - Direct observation of rotational energy transfer in ammonia by time-resolved infrared-microwave double resonance

AU - Levy, J. M.

AU - Wang, J. H.S.

AU - Kukolich, S. G.

AU - Steinfeld, J. I.

N1 - Funding Information: * Work supported by Air Force Office of Scientific under grant AFOSR-7 l-2032.

PY - 1973/9/1

Y1 - 1973/9/1

N2 - An N2O laser is used to pump the ground vibrational state (8,7) inversion doublet of 14NH3 while simultaneously monitoring other ground state doublets. Time-resolved rotational energy transfer signals are observed in accordance with known selection values. Absolute rates of rotational energy transfer processes are estimated.

AB - An N2O laser is used to pump the ground vibrational state (8,7) inversion doublet of 14NH3 while simultaneously monitoring other ground state doublets. Time-resolved rotational energy transfer signals are observed in accordance with known selection values. Absolute rates of rotational energy transfer processes are estimated.

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U2 - 10.1016/0009-2614(73)80318-5

DO - 10.1016/0009-2614(73)80318-5

M3 - Article

AN - SCOPUS:49549163877

SN - 0009-2614

VL - 21

SP - 598

EP - 602

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 3

ER -

Direct observation of rotational energy transfer in ammonia by time-resolved infrared-microwave double resonance

Abstract

ASJC Scopus subject areas

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