Direct hydrolytic route to molecular oxo-hydroxo lanthanide clusters

Ruiyao Wang; Michael D. Carducci; Zhiping Zheng

doi:10.1021/ic991391p

Direct hydrolytic route to molecular oxo-hydroxo lanthanide clusters

Ruiyao Wang, Michael D. Carducci, Zhiping Zheng

Research output: Contribution to journal › Article › peer-review

110 Scopus citations

Abstract

Direct hydrolysis of Er(NO₃)₃, Nd(ClO₄)₃, and Gd-(ClO₄)₃ with aqueous NaOH afforded three hexanuclear lanthanide clusters with a common octahedral core of [Ln₆(μ₆-O)(μ₃-OH)₈]⁸⁺ whose six lanthanide ions center on a μ₆-oxo ligand. Each of the triangular faces of the octahedron is capped by a μ₃-OH ligand, and the coordination sphere of the metal is completed by both aqua and NO₃^- ligands (1), aqua ligands only (2), and both aqua and ClO₄^- ligands (3).

Original language	English (US)
Pages (from-to)	1836-1837
Number of pages	2
Journal	Inorganic Chemistry
Volume	39
Issue number	9
DOIs	https://doi.org/10.1021/ic991391p
State	Published - May 1 2000
Externally published	Yes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry

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title = "Direct hydrolytic route to molecular oxo-hydroxo lanthanide clusters",

abstract = "Direct hydrolysis of Er(NO3)3, Nd(ClO4)3, and Gd-(ClO4)3 with aqueous NaOH afforded three hexanuclear lanthanide clusters with a common octahedral core of [Ln6(μ6-O)(μ3-OH)8]8+ whose six lanthanide ions center on a μ6-oxo ligand. Each of the triangular faces of the octahedron is capped by a μ3-OH ligand, and the coordination sphere of the metal is completed by both aqua and NO3- ligands (1), aqua ligands only (2), and both aqua and ClO4- ligands (3).",

author = "Ruiyao Wang and Carducci, {Michael D.} and Zhiping Zheng",

year = "2000",

month = may,

day = "1",

doi = "10.1021/ic991391p",

language = "English (US)",

volume = "39",

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journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

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T1 - Direct hydrolytic route to molecular oxo-hydroxo lanthanide clusters

AU - Wang, Ruiyao

AU - Carducci, Michael D.

AU - Zheng, Zhiping

PY - 2000/5/1

Y1 - 2000/5/1

N2 - Direct hydrolysis of Er(NO3)3, Nd(ClO4)3, and Gd-(ClO4)3 with aqueous NaOH afforded three hexanuclear lanthanide clusters with a common octahedral core of [Ln6(μ6-O)(μ3-OH)8]8+ whose six lanthanide ions center on a μ6-oxo ligand. Each of the triangular faces of the octahedron is capped by a μ3-OH ligand, and the coordination sphere of the metal is completed by both aqua and NO3- ligands (1), aqua ligands only (2), and both aqua and ClO4- ligands (3).

AB - Direct hydrolysis of Er(NO3)3, Nd(ClO4)3, and Gd-(ClO4)3 with aqueous NaOH afforded three hexanuclear lanthanide clusters with a common octahedral core of [Ln6(μ6-O)(μ3-OH)8]8+ whose six lanthanide ions center on a μ6-oxo ligand. Each of the triangular faces of the octahedron is capped by a μ3-OH ligand, and the coordination sphere of the metal is completed by both aqua and NO3- ligands (1), aqua ligands only (2), and both aqua and ClO4- ligands (3).

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JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 9

ER -

Direct hydrolytic route to molecular oxo-hydroxo lanthanide clusters

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