Direct, highly enantioselective pyrrolidine sulfonamide catalyzed Michael addition of aldehydes to nitrostyrenes

Wei Wang; Jian Wang; Hao Li

doi:10.1002/anie.200461959

Direct, highly enantioselective pyrrolidine sulfonamide catalyzed Michael addition of aldehydes to nitrostyrenes

Wei Wang, Jian Wang, Hao Li

Research output: Contribution to journal › Article › peer-review

379 Scopus citations

Abstract

Just can't get enough: The highly versatile pyrrolidine sulfonamide organocatalyst 1, which has been used in α-aminoxylation and Mannich-type reactions, also mediates diastereo- and enantioselective Michael addition reactions of aldehydes and ketones to nitroolefins (see scheme).

Original language	English (US)
Pages (from-to)	1369-1371
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	44
Issue number	9
DOIs	https://doi.org/10.1002/anie.200461959
State	Published - Feb 18 2005
Externally published	Yes

Keywords

Aldehydes
Asymmetric catalysis
Michael addition
Nitroalkenes
Organocatalysts

ASJC Scopus subject areas

Catalysis
General Chemistry

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10.1002/anie.200461959

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title = "Direct, highly enantioselective pyrrolidine sulfonamide catalyzed Michael addition of aldehydes to nitrostyrenes",

abstract = "Just can't get enough: The highly versatile pyrrolidine sulfonamide organocatalyst 1, which has been used in α-aminoxylation and Mannich-type reactions, also mediates diastereo- and enantioselective Michael addition reactions of aldehydes and ketones to nitroolefins (see scheme).",

keywords = "Aldehydes, Asymmetric catalysis, Michael addition, Nitroalkenes, Organocatalysts",

author = "Wei Wang and Jian Wang and Hao Li",

year = "2005",

month = feb,

day = "18",

doi = "10.1002/anie.200461959",

language = "English (US)",

volume = "44",

pages = "1369--1371",

journal = "Angewandte Chemie - International Edition",

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publisher = "John Wiley and Sons Ltd",

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T1 - Direct, highly enantioselective pyrrolidine sulfonamide catalyzed Michael addition of aldehydes to nitrostyrenes

AU - Wang, Wei

AU - Wang, Jian

AU - Li, Hao

PY - 2005/2/18

Y1 - 2005/2/18

N2 - Just can't get enough: The highly versatile pyrrolidine sulfonamide organocatalyst 1, which has been used in α-aminoxylation and Mannich-type reactions, also mediates diastereo- and enantioselective Michael addition reactions of aldehydes and ketones to nitroolefins (see scheme).

AB - Just can't get enough: The highly versatile pyrrolidine sulfonamide organocatalyst 1, which has been used in α-aminoxylation and Mannich-type reactions, also mediates diastereo- and enantioselective Michael addition reactions of aldehydes and ketones to nitroolefins (see scheme).

KW - Aldehydes

KW - Asymmetric catalysis

KW - Michael addition

KW - Nitroalkenes

KW - Organocatalysts

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U2 - 10.1002/anie.200461959

DO - 10.1002/anie.200461959

M3 - Article

AN - SCOPUS:14844316261

SN - 1433-7851

VL - 44

SP - 1369

EP - 1371

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 9

ER -

Direct, highly enantioselective pyrrolidine sulfonamide catalyzed Michael addition of aldehydes to nitrostyrenes

Abstract

Keywords

ASJC Scopus subject areas

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