Deuterium quadrupole coupling in formyl fluoride

Stephen G. Kukolich

doi:10.1063/1.1676126

Deuterium quadrupole coupling in formyl fluoride

Stephen G. Kukolich

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

The 1₀₁-0₀₀ rotational transition in HFCO and DFCO was recorded with a beam maser spectrometer. Hyperfine structure due to the deuterium quadrupole coupling was observed for DFCO. Analysis of the spectrum yielded the deuterium quadrupole coupling strength along the D-C bond direction of eqQ=205.± 4. kHz. This rotational transition had not been reported previously for DFCO. A comparison of deuterium quadrupole coupling strengths with force constants along the H-C bond is made according to the theory of Salem.

Original language	English (US)
Pages (from-to)	610-612
Number of pages	3
Journal	The Journal of chemical physics
Volume	55
Issue number	2
DOIs	https://doi.org/10.1063/1.1676126
State	Published - 1971
Externally published	Yes

ASJC Scopus subject areas

General Physics and Astronomy
Physical and Theoretical Chemistry

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10.1063/1.1676126

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title = "Deuterium quadrupole coupling in formyl fluoride",

abstract = "The 101-000 rotational transition in HFCO and DFCO was recorded with a beam maser spectrometer. Hyperfine structure due to the deuterium quadrupole coupling was observed for DFCO. Analysis of the spectrum yielded the deuterium quadrupole coupling strength along the D-C bond direction of eqQ=205.± 4. kHz. This rotational transition had not been reported previously for DFCO. A comparison of deuterium quadrupole coupling strengths with force constants along the H-C bond is made according to the theory of Salem.",

author = "Kukolich, \{Stephen G.\}",

year = "1971",

doi = "10.1063/1.1676126",

language = "English (US)",

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pages = "610--612",

journal = "The Journal of chemical physics",

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publisher = "American Institute of Physics",

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T1 - Deuterium quadrupole coupling in formyl fluoride

AU - Kukolich, Stephen G.

PY - 1971

Y1 - 1971

N2 - The 101-000 rotational transition in HFCO and DFCO was recorded with a beam maser spectrometer. Hyperfine structure due to the deuterium quadrupole coupling was observed for DFCO. Analysis of the spectrum yielded the deuterium quadrupole coupling strength along the D-C bond direction of eqQ=205.± 4. kHz. This rotational transition had not been reported previously for DFCO. A comparison of deuterium quadrupole coupling strengths with force constants along the H-C bond is made according to the theory of Salem.

AB - The 101-000 rotational transition in HFCO and DFCO was recorded with a beam maser spectrometer. Hyperfine structure due to the deuterium quadrupole coupling was observed for DFCO. Analysis of the spectrum yielded the deuterium quadrupole coupling strength along the D-C bond direction of eqQ=205.± 4. kHz. This rotational transition had not been reported previously for DFCO. A comparison of deuterium quadrupole coupling strengths with force constants along the H-C bond is made according to the theory of Salem.

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U2 - 10.1063/1.1676126

DO - 10.1063/1.1676126

M3 - Article

AN - SCOPUS:36849099347

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VL - 55

SP - 610

EP - 612

JO - The Journal of chemical physics

JF - The Journal of chemical physics

IS - 2

ER -

Deuterium quadrupole coupling in formyl fluoride

Abstract

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